{"id":"W4288037828","doi":"10.1002/chem.202201565","title":"Reactivity of Primary Phosphines and Primary Phosphine Sulfides towards Imines","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario; Nuclear Waste Management Organization","keywords":"Reactivity (psychology); Phosphine; Chemistry; Nucleophile; Primary (astronomy); Imine; Medicinal chemistry; Tautomer; Kinetic isotope effect; Stoichiometry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001062594,0.0004188374,0.0006103571,0.00004993201,0.00052763,0.0001094798,0.0007992673,0.00005033308,0.004215952],"category_scores_gemma":[0.0002576439,0.0004227238,0.0002295594,0.0002384534,0.0002699313,0.0002103664,0.001026901,0.001013557,0.000006010124],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003640292,"about_ca_system_score_gemma":0.0002670698,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001600027,"about_ca_topic_score_gemma":2.520177e-7,"domain_scores_codex":[0.9974453,0.0001118495,0.0007632841,0.0005031969,0.0007300287,0.0004463154],"domain_scores_gemma":[0.9980711,0.0001604268,0.0007218695,0.0006194236,0.0001413745,0.0002858098],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002931192,0.0003257735,0.00416905,0.0005105654,0.0001221744,0.0004762992,0.0002938042,0.00001386917,0.9673745,0.000001523717,0.002881097,0.02353823],"study_design_scores_gemma":[0.001457748,0.00006323565,0.01237468,0.0001344052,0.0001307093,0.003696443,0.000403746,0.00006054508,0.9426187,0.0001052996,0.03835602,0.0005984501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9487346,0.003073416,0.00001268291,0.0003799257,0.0001388043,0.00004390387,0.0001026714,0.0001035398,0.04741043],"genre_scores_gemma":[0.9942343,0.0005881546,0.0009371032,0.0001252903,0.0004534838,0.000006801985,0.00004299978,0.0001318117,0.003480114],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04549961,"threshold_uncertainty_score":0.9998224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168007280448781,"score_gpt":0.1879590891164839,"score_spread":0.1762790163119961,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}