{"id":"W4288077309","doi":"10.1002/cjce.24576","title":"Catalytic oxidation of glycerol in alkaline medium – Influence of mass transport limitations","year":2022,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Catalysis for Biomass Conversion","field":"Engineering","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Catalysis; Chemistry; Glycerol; Mass transfer; Selectivity; Redox; Reaction rate; Reaction mechanism; Metal; Reaction intermediate; Mass transport; Kinetic control; Inorganic chemistry; Chemical engineering; Organic chemistry; Chromatography; Biochemical engineering","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003183851,0.000340252,0.0003361157,0.0001632538,0.0001882664,0.0006745009,0.0004548793,0.0003147751,0.0007195779],"category_scores_gemma":[0.0008027698,0.0001634179,0.0001600723,0.000220668,0.000412301,0.0004784078,0.0004017789,0.0006104367,0.0001071145],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003473216,"about_ca_system_score_gemma":0.0003207411,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004896638,"about_ca_topic_score_gemma":0.00466129,"domain_scores_codex":[0.9996808,0.00006158289,0.0000240513,0.00004102751,0.0001147777,0.00007776089],"domain_scores_gemma":[0.9996508,0.0001918635,0.00005810427,0.00001989305,0.00005833424,0.00002083207],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002973918,0.00003253546,0.0002994397,0.0001382622,0.00002005841,0.0001093404,0.00006116914,0.0007143538,0.9964761,0.0001756065,0.00003409407,0.001641486],"study_design_scores_gemma":[0.000008628844,0.0001436867,0.0005629705,0.000006703175,0.00001536799,0.00003447067,0.00006936344,0.002400541,0.9962898,0.00003471854,0.0004264316,0.000007257557],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980598,0.0003806098,0.0007700365,0.00005548642,0.00001134523,0.000008456897,0.00005451003,0.0000103503,0.0006495083],"genre_scores_gemma":[0.9991533,0.00028515,0.0003324588,0.000006131871,0.000002923549,0.000003950265,0.00004364989,0.000003394689,0.0001690337],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004896638,"threshold_uncertainty_score":0.0097363,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007391087734242174,"score_gpt":0.1690565141740557,"score_spread":0.1616654264398135,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}