{"id":"W4288077717","doi":"10.1021/acsomega.2c02286","title":"Synthesis, Catalytic GPx-like Activity, and SET Reactions of Conformationally Constrained 2,7-Dialkoxy-Substituted Naphthalene-1,8-<i>peri-</i>diselenides","year":2022,"lang":"en","type":"article","venue":"ACS Omega","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Naphthalene; Thiol; Hydrogen peroxide; Triethylamine; Medicinal chemistry; Peroxidase; Antioxidant; Photochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001384021,0.0004313242,0.0002194115,0.0001240038,0.0001413731,0.0002209495,0.000277568,0.0002856971,0.001060066],"category_scores_gemma":[0.0002017613,0.000128626,0.0002563264,0.000148191,0.0002130648,0.0002544713,0.0001815207,0.0004793872,0.0003310276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002426945,"about_ca_system_score_gemma":0.0002225059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003720987,"about_ca_topic_score_gemma":0.0007056792,"domain_scores_codex":[0.9999102,0.00001602184,0.000008459538,0.0000197218,0.00002356813,0.0000219641],"domain_scores_gemma":[0.9999428,0.00001349574,0.00001328596,0.000008560954,0.000007529353,0.00001445569],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007800513,0.00001930226,0.00004646537,0.00003829324,0.000007928481,0.00005100084,0.00003809055,0.0001280675,0.9970495,0.0005439089,0.00007425887,0.001925236],"study_design_scores_gemma":[0.00000465425,0.00005426437,0.0001029543,0.000001301632,0.000002532567,0.00004188433,0.000004476955,0.00008923122,0.9992214,0.00003184962,0.0004435299,0.000001929224],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9856592,0.0007424405,0.008636232,0.0001077508,0.00003456262,0.00004913739,0.0003846166,0.0001335743,0.004252556],"genre_scores_gemma":[0.9916615,0.0007135173,0.003427752,0.00002943986,0.000006561695,0.00003028096,0.0004978857,0.00004983401,0.00358313],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001060066,"threshold_uncertainty_score":0.003546298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05335052009580301,"score_gpt":0.3459116828802418,"score_spread":0.2925611627844388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}