{"id":"W4288781634","doi":"10.1039/d2ee00803c","title":"Different interfacial reactivity of lithium metal chloride electrolytes with high voltage cathodes determines solid-state battery performance","year":2022,"lang":"en","type":"article","venue":"Energy & Environmental Science","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":126,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; Office of Science; Basic Energy Sciences; Bundesministerium für Bildung und Forschung; U.S. Department of Energy","keywords":"Lithium metal; Electrolyte; Cathode; Interphase; Battery (electricity); Reactivity (psychology); Lithium (medication); Materials science; Metal; Chloride; Inorganic chemistry; Solid-state; Chemical engineering; Potassium-ion battery; Lithium chloride; Fast ion conductor; Chemistry; Lithium vanadium phosphate battery; Electrode; Metallurgy; Physical chemistry; Thermodynamics; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001103913,0.0002051974,0.0002315926,0.0001067712,0.0002263001,0.00002275477,0.0004097261,0.00001987871,0.00007980324],"category_scores_gemma":[0.000003653404,0.0001657003,0.00002951573,0.0001565784,0.0004973888,0.0004029557,0.0003665017,0.000128084,0.000001674611],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002026488,"about_ca_system_score_gemma":0.000008882182,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002793145,"about_ca_topic_score_gemma":0.000009697494,"domain_scores_codex":[0.9987631,0.00001371013,0.0001942704,0.0003027533,0.0003501331,0.0003760496],"domain_scores_gemma":[0.9995989,0.00002326418,0.00007671599,0.0002558049,0.000002903669,0.00004237357],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004424876,0.00005070923,0.002000577,0.000008841361,0.000009616137,0.00000614875,0.00007190352,0.02674362,0.9644136,0.00002249038,0.000001626974,0.0066266],"study_design_scores_gemma":[0.0001336914,0.0002824802,0.0212026,0.000007032277,0.000008344177,0.00002379391,0.00007011036,0.002371202,0.9753269,0.00006680241,0.0003034257,0.0002036402],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974747,0.00004601202,0.001948323,0.00001052578,0.0002279484,0.00005554672,0.00004196011,0.0001248334,0.00007015457],"genre_scores_gemma":[0.999505,0.0001033965,0.0001757213,0.00001713045,0.0000227169,0.0000715366,0.000007506648,0.00002160684,0.0000753293],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02437242,"threshold_uncertainty_score":0.6757061,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003978664517460372,"score_gpt":0.1720892261442812,"score_spread":0.1681105616268208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}