{"id":"W4289308100","doi":"10.1002/ange.202205963","title":"The Synthetic Potential of Thiophenium Ylide Cycloadducts**","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa","keywords":"Cycloaddition; Ylide; Intramolecular force; Chemistry; Combinatorial chemistry; Sulfide; Atom (system on chip); Computational chemistry; Lewis acids and bases; Stereochemistry; Organic chemistry; Catalysis; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001382621,0.0001269765,0.000138122,0.00000981758,0.00058834,0.00002082502,0.0005111683,0.00004813895,0.002510638],"category_scores_gemma":[0.00005446433,0.0001086136,0.0001356311,0.0001504041,0.0001406348,0.00002593343,0.0002689676,0.0002837651,0.0000122699],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000562338,"about_ca_system_score_gemma":0.00005280585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002328314,"about_ca_topic_score_gemma":0.000001623204,"domain_scores_codex":[0.9989728,0.000009266078,0.0002543803,0.0002416505,0.0002821891,0.0002396634],"domain_scores_gemma":[0.9989868,0.0001435906,0.0001492869,0.0006166606,0.00004249042,0.00006115987],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000290727,0.00008034935,0.00003853364,0.00003926825,0.00003266684,0.000003951802,0.0000849592,0.00003491757,0.9933228,0.0003135042,0.005603873,0.0004161178],"study_design_scores_gemma":[0.0001913899,0.00000478372,0.00001136508,0.000006078229,0.0000357254,0.00003432053,0.0006188933,0.000009948508,0.8535997,0.000751327,0.1446281,0.0001083596],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.905299,0.00081677,0.00000883003,0.001606214,0.00009518499,0.00006476702,0.0001691416,0.00008286389,0.09185721],"genre_scores_gemma":[0.9898992,0.00007514989,0.00003237805,0.00005889389,0.000181173,0.0001512762,0.00007003103,0.00001997385,0.009511931],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1397231,"threshold_uncertainty_score":0.9984012,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009610500395071789,"score_gpt":0.2248404744589723,"score_spread":0.2152299740639005,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}