{"id":"W4289524817","doi":"10.1002/cptc.202200181","title":"Coherent Intramolecular Excimer Formation in Solid [2,2]‐Paracyclophane: Time‐Resolved Springing of a Molecular “Trap”","year":2022,"lang":"en","type":"article","venue":"ChemPhotoChem","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Azrieli Foundation","keywords":"Intramolecular force; Excimer; Excited state; Ring (chemistry); Molecular physics; Dipole; Spectroscopy; Chemistry; Absorption spectroscopy; Excitation; Atomic physics; Chemical physics; Photochemistry; Fluorescence; Physics; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000835009,0.00009067969,0.00009560609,0.00009910008,0.000200219,0.0002111337,0.0001852199,0.0001437092,0.001727508],"category_scores_gemma":[0.0001776408,0.0001161072,0.00007037732,0.0001070102,0.0003153368,0.0002324143,0.0001447167,0.0004337737,0.0001250852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001942426,"about_ca_system_score_gemma":0.0001087635,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004706907,"about_ca_topic_score_gemma":0.0006837294,"domain_scores_codex":[0.9999588,0.000004147405,8.783051e-7,0.00001167835,0.00001227695,0.00001230135],"domain_scores_gemma":[0.999892,0.00004372797,0.00002753164,0.00001117216,0.00001062707,0.00001493991],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009169769,0.00004105368,0.0006340221,0.00003025741,0.000007663956,0.0001425758,0.0001280647,0.0005613961,0.9951233,0.000561387,0.00008411973,0.002594403],"study_design_scores_gemma":[0.00002365951,0.0002340172,0.008812288,0.000006634437,0.00001039651,0.000142027,0.0001103501,0.01768864,0.9721199,0.0002361245,0.0006029581,0.00001307927],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985529,0.00003557985,0.0008833573,0.00001350544,0.000002392899,0.000002304454,0.00001408268,0.00001596208,0.0004800006],"genre_scores_gemma":[0.9991739,0.00002505074,0.0003933893,0.000006219712,0.000001244349,0.000002466226,0.00001874908,0.00000503089,0.0003739765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001727508,"threshold_uncertainty_score":0.005779147,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0071452019139985,"score_gpt":0.2277201556488516,"score_spread":0.2205749537348531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}