{"id":"W4289947430","doi":"10.1002/ange.202210340","title":"Homogeneous Synthesis of Monodisperse Sequence‐Defined Conjugated Oligomers by Temperature Cycling","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Monomer; Sequence (biology); Conjugated system; Polymer; Dispersity; Folding (DSP implementation); Materials science; Oligomer; Homogeneous; Chemistry; Combinatorial chemistry; Nanotechnology; Polymer chemistry; Organic chemistry; Mathematics; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007445927,0.000226331,0.0003316545,0.00004502372,0.0002263755,0.00001958522,0.0002697835,0.0001050357,0.002378937],"category_scores_gemma":[0.00007293267,0.0002385237,0.0001308444,0.0002114697,0.0000781213,0.00008857965,0.0000963525,0.0002186062,0.000005607487],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001067794,"about_ca_system_score_gemma":0.00004872427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004139559,"about_ca_topic_score_gemma":0.000001201844,"domain_scores_codex":[0.9987266,0.00002125463,0.0003420924,0.0003506443,0.000273353,0.0002860427],"domain_scores_gemma":[0.9991435,0.000119435,0.0002406284,0.0003617863,0.00004534018,0.00008927172],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006618829,0.00008938136,0.0002672226,0.00007257462,0.00007167977,0.00001461918,0.000209117,0.00004372124,0.9971961,0.00001824633,0.0006916983,0.001259386],"study_design_scores_gemma":[0.0002340443,0.00001276441,0.00000583197,0.00003399772,0.00006217891,0.00002118375,0.0007094601,0.0000281627,0.9897922,0.00001550425,0.008818356,0.0002663636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910261,0.001074292,0.000004158579,0.0001550426,0.00007422648,0.00005850998,0.001121525,0.0001021488,0.006383979],"genre_scores_gemma":[0.9972052,0.0002150689,0.00009323139,0.0001461884,0.00007002731,0.0001126862,0.0005067735,0.00005098297,0.001599852],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008126657,"threshold_uncertainty_score":0.998533,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01204910376654274,"score_gpt":0.2266943132532646,"score_spread":0.2146452094867218,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}