{"id":"W4290098514","doi":"10.1055/s-0042-1751354","title":"The Awakening of a Sleeping Beauty: The ortho Photocycloaddition in the Total Synthesis of Protoilludane- and Prezizaene-Type Sesquiterpenes","year":2022,"lang":"en","type":"article","venue":"Synlett","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Stereocenter; Intramolecular force; Domino; Stereochemistry; Sesquiterpene; Sequence (biology); Propellane; Total synthesis; Cascade; Cycloaddition; Bicyclic molecule; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005666787,0.0001253873,0.000164735,0.00002243523,0.0004144409,0.00002319115,0.0003444681,0.00005241888,0.0004449928],"category_scores_gemma":[0.0004582407,0.00007600481,0.00006239345,0.0002948147,0.0001965304,0.00004577492,0.0002027861,0.0004049851,8.290389e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006649869,"about_ca_system_score_gemma":0.00006730575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009141422,"about_ca_topic_score_gemma":0.00001940161,"domain_scores_codex":[0.9988478,0.0001251019,0.0003106198,0.0001948011,0.0003277637,0.000193842],"domain_scores_gemma":[0.9980339,0.001187157,0.0002627062,0.0004557875,0.00004129425,0.00001911618],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006538264,0.00007503411,0.002832433,0.0001287169,0.00006508215,0.000004705723,0.001444268,0.00008560799,0.9923558,0.0001099482,0.0001686392,0.002664366],"study_design_scores_gemma":[0.0002612374,0.0000334718,0.004085504,0.0001226182,0.00007581022,0.0001788971,0.008275497,0.0005132579,0.9792475,0.0001569379,0.00688955,0.0001596838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937202,0.0002114603,0.000003154037,0.0008631462,0.00003555341,0.0003760239,0.00008452518,0.00001841163,0.004687509],"genre_scores_gemma":[0.9990882,0.0000199248,0.000024239,0.00002878649,0.00004912585,0.0005874569,0.00001264188,0.00001749959,0.0001721637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01310828,"threshold_uncertainty_score":0.4872359,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009760973169773118,"score_gpt":0.2304524582859008,"score_spread":0.2206914851161277,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}