{"id":"W4292417338","doi":"10.1016/j.jhazmat.2022.129798","title":"Aqueous naphthenic acids and polycyclic aromatic hydrocarbons in a meso-scale spill tank affected by diluted bitumen analyzed directly by membrane introduction mass spectrometry","year":2022,"lang":"en","type":"article","venue":"Journal of Hazardous Materials","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"Simon Fraser University; University of Victoria; Natural Resources Canada; Vancouver Island University","funders":"British Columbia Knowledge Development Fund; Natural Sciences and Engineering Research Council of Canada; Government of Canada; Natural Resources Canada; Vancouver Island University","keywords":"Chemistry; Mass spectrometry; Environmental chemistry; Electrospray ionization; Mesocosm; Aqueous solution; Chromatography; Triple quadrupole mass spectrometer; Analytical Chemistry (journal); Tandem mass spectrometry; Selected reaction monitoring; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001130221,0.0002952793,0.0002480063,0.0002340374,0.000365898,0.0003774985,0.0002062436,0.0004787974,0.000835259],"category_scores_gemma":[0.0001243678,0.0001494241,0.0002265341,0.0001361536,0.0002909775,0.0002784424,0.0002657756,0.0004000138,0.0002141998],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003618954,"about_ca_system_score_gemma":0.0003580719,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004156459,"about_ca_topic_score_gemma":0.004193131,"domain_scores_codex":[0.9998666,0.000009801602,0.000006832358,0.00003493458,0.00005139366,0.00003053183],"domain_scores_gemma":[0.9999244,0.00001888407,0.00001948219,0.000004050172,0.00001792502,0.00001532276],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004108771,0.00002955915,0.002245173,0.00001296934,0.00001095968,0.0001249863,0.00002939089,0.0002315921,0.9961546,0.00001662066,0.0000203065,0.0007129729],"study_design_scores_gemma":[0.0000139547,0.0004081394,0.01743896,0.000003795073,0.00003209472,0.000124739,0.000173776,0.003796406,0.9776785,0.00003724022,0.0002815457,0.00001079576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990399,0.00004466712,0.000504211,0.00002137117,0.000006278416,0.000003981802,0.0001048902,0.00002208999,0.0002525637],"genre_scores_gemma":[0.998037,0.00006382089,0.0006792724,0.00002224506,0.00000291516,0.000004821082,0.000124939,0.000006739887,0.001058183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004156459,"threshold_uncertainty_score":0.008264542,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003315687875470354,"score_gpt":0.2052858105265774,"score_spread":0.2019701226511071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}