{"id":"W4292455953","doi":"10.1002/cbic.202200285","title":"Phosphoenolpyruvate Mutase‐Catalyzed C−P Bond Formation: Mechanistic Ambiguities and Opportunities","year":2022,"lang":"en","type":"review","venue":"ChemBioChem","topic":"Biochemical and Molecular Research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Phosphoenolpyruvate carboxykinase; Stereochemistry; Mutase; Enzyme; Intramolecular force; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008901666,0.001015463,0.001223875,0.001525219,0.000369144,0.001328843,0.001542461,0.001407885,0.003573649],"category_scores_gemma":[0.0008723812,0.000559142,0.0004370652,0.002215925,0.0009083465,0.002387405,0.0009575137,0.00237541,0.003213327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001100906,"about_ca_system_score_gemma":0.001393749,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001206365,"about_ca_topic_score_gemma":0.002023568,"domain_scores_codex":[0.9997945,0.00002683568,0.00002091765,0.00004933337,0.0000682701,0.00004001224],"domain_scores_gemma":[0.9996891,0.0001410879,0.00004015289,0.00001595281,0.00007786691,0.00003589786],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001302966,0.0000839986,0.0001300265,0.02180639,0.00008495674,0.0003684964,0.00009151597,0.0008550063,0.005290066,0.02569487,0.04148206,0.9039822],"study_design_scores_gemma":[0.000009940794,0.00006356417,0.0001502412,0.001063845,0.00003901247,0.0004089011,0.00003339877,0.00009182775,0.001138292,0.002598863,0.9943874,0.00001465661],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0002147589,0.9967758,0.0002797999,0.0003619309,0.0002850294,0.000004864663,0.00002588428,0.00001339017,0.002038464],"genre_scores_gemma":[0.001077019,0.9974607,0.0002362828,0.0002102236,0.00009734488,0.000006422177,0.00003453949,0.000002932133,0.0008743932],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.003573649,"threshold_uncertainty_score":0.01195508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1010797801753511,"score_gpt":0.3187295369544899,"score_spread":0.2176497567791387,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}