{"id":"W4292723031","doi":"10.1002/asia.202200727","title":"Enhanced Electrochemiluminescence of A Macrocyclic Tetradentate Chelate Pt(II) Molecule through Its Collisional Interactions with the Electrode","year":2022,"lang":"en","type":"article","venue":"Chemistry - An Asian Journal","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; Western University","funders":"","keywords":"Electrochemiluminescence; Luminophore; Monomer; Chemistry; Excited state; Molecule; Dimethylformamide; Photochemistry; Dichloromethane; Excimer; Electrode; Solvent; Luminescence; Physical chemistry; Fluorescence; Materials science; Organic chemistry; Optoelectronics; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002263968,0.0002665109,0.0002030154,0.0001346104,0.0001040682,0.0002564007,0.0003136278,0.0003385465,0.0009327106],"category_scores_gemma":[0.0002113835,0.0001584294,0.0001649506,0.0001231436,0.0002024116,0.0002248482,0.0002391479,0.0003710822,0.0002610872],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002815435,"about_ca_system_score_gemma":0.0001014512,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002143172,"about_ca_topic_score_gemma":0.0002716364,"domain_scores_codex":[0.9998392,0.00002573496,0.000006723419,0.00004937804,0.00004563561,0.00003337155],"domain_scores_gemma":[0.9999325,0.00002090279,0.00001531336,0.00000552219,0.00001219193,0.00001368469],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002006849,0.000004918596,0.00003013629,0.0000149932,0.000002073825,0.00003336553,0.00001190051,0.00002507421,0.9991956,0.00007540266,0.00003435308,0.0005521937],"study_design_scores_gemma":[0.00000369354,0.0000463658,0.0002258367,0.000001127144,0.000003284576,0.00006029556,0.000003403077,0.0005100803,0.9986556,0.00001102227,0.0004779741,0.000001250493],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9743062,0.001133534,0.0214923,0.0002008077,0.00006495231,0.00002537258,0.00007968512,0.0002567344,0.002440524],"genre_scores_gemma":[0.9887415,0.0003521348,0.007830185,0.00008271341,0.00001377712,0.0000209447,0.00008190788,0.00001906348,0.002857761],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009327106,"threshold_uncertainty_score":0.003120244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006563634613604884,"score_gpt":0.2635291240311302,"score_spread":0.2569654894175253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}