{"id":"W4292836749","doi":"10.1002/ange.202209143","title":"Photoredox Activation of Anhydrides for the Solvent‐Controlled Switchable Synthesis of <i>gem</i>‐Difluoro Compounds**","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"SNC-Lavalin (Canada)","funders":"Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Chemistry; Alkene; Reagent; Regioselectivity; Combinatorial chemistry; Solvent; Bond cleavage; Electron transfer; Molecule; Photocatalysis; Functional group; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001615179,0.0004157923,0.0001111358,0.0001278481,0.00008874085,0.0001349248,0.000241042,0.000239282,0.001333426],"category_scores_gemma":[0.0001411762,0.000112222,0.0001410387,0.0001181444,0.0001492017,0.0002853391,0.0001532689,0.0003363778,0.0003412899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003262516,"about_ca_system_score_gemma":0.0001716928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005674461,"about_ca_topic_score_gemma":0.00123674,"domain_scores_codex":[0.9999135,0.00001096776,0.000005773039,0.00002475502,0.00001650854,0.00002864029],"domain_scores_gemma":[0.9999484,0.00001045475,0.00002060226,0.000005648406,0.000006119924,0.000008845614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003688334,0.000009821493,0.00004799813,0.00006120119,0.000002851531,0.00006376414,0.00002021189,0.0001032108,0.9961373,0.0006758217,0.0001673771,0.002673495],"study_design_scores_gemma":[0.000006168356,0.00007473025,0.0002432323,0.000002678879,0.000002377131,0.00008120072,0.000005574505,0.0004383002,0.9954465,0.00003876311,0.003656053,0.000004458754],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9510211,0.003890817,0.02561886,0.0003145538,0.0001444123,0.0001312255,0.0004950935,0.0004558909,0.01792797],"genre_scores_gemma":[0.9906025,0.001234529,0.005363431,0.00007007093,0.00001726566,0.00002811705,0.000131783,0.00003780403,0.002514428],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001333426,"threshold_uncertainty_score":0.004460692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06310520698401499,"score_gpt":0.3550922532169358,"score_spread":0.2919870462329208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}