{"id":"W4294397808","doi":"10.1039/d2dt02177c","title":"Vanadium pyridonates: dimerization, redox behaviour, and metal–ligand cooperativity","year":2022,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Vanadium; Cooperativity; Chemistry; Redox; Reactivity (psychology); Ligand (biochemistry); Metal; Amine gas treating; Crystallography; Stereochemistry; Inorganic chemistry; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000934004,0.0002030741,0.0001455243,0.00008910523,0.0001329576,0.000358376,0.0003203652,0.0001920079,0.0005190431],"category_scores_gemma":[0.0001705882,0.0001367026,0.00008266087,0.0001156052,0.0001721993,0.0002337607,0.0001635899,0.000296965,0.0001478334],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003722184,"about_ca_system_score_gemma":0.0001075102,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008120749,"about_ca_topic_score_gemma":0.001639053,"domain_scores_codex":[0.9999101,0.00001519547,0.000005865743,0.00002844047,0.00002331829,0.00001702075],"domain_scores_gemma":[0.9999648,0.000009448195,0.00001018807,0.000003583754,0.000005539121,0.00000651349],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007146944,0.00001133562,0.0001678939,0.00005977757,0.000006338882,0.00005403117,0.00003210633,0.0002919137,0.9952252,0.001075279,0.00005006645,0.002954698],"study_design_scores_gemma":[0.000008208248,0.0001135628,0.0006727008,0.000004923208,0.000007306012,0.0002889599,0.00003806801,0.001691685,0.9916711,0.0003185539,0.005175739,0.000009303328],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842095,0.003840085,0.005901521,0.0001483363,0.00002638626,0.00003245658,0.0000926134,0.00004647293,0.005702502],"genre_scores_gemma":[0.9948522,0.001034517,0.002162886,0.00003211631,0.000004405698,0.00000831396,0.00008574549,0.000008900679,0.001810969],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008120749,"threshold_uncertainty_score":0.002700627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01092534978298218,"score_gpt":0.2264595381268762,"score_spread":0.2155341883438941,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}