{"id":"W4294636308","doi":"10.1039/d2dt02855g","title":"Reactions of a Lewis acidic methylene phosphonium cationic adduct with olefins","year":2022,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto","keywords":"Phosphonium; Cationic polymerization; Chemistry; Adduct; Lewis acids and bases; Methylene; Medicinal chemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002077961,0.0003265668,0.000169285,0.0001340886,0.0001704487,0.0001417163,0.0002726086,0.0003601194,0.002434628],"category_scores_gemma":[0.0002201151,0.0001253283,0.0001362839,0.0001324734,0.0001824724,0.0002109587,0.0002923585,0.0003450538,0.0003638184],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002272742,"about_ca_system_score_gemma":0.0001963848,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004592365,"about_ca_topic_score_gemma":0.0007418098,"domain_scores_codex":[0.9998726,0.00001509052,0.000007127881,0.00002449498,0.00003239239,0.00004825706],"domain_scores_gemma":[0.999913,0.00001491358,0.00002087268,0.00001020336,0.00001096386,0.00003008944],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001590452,0.0000135821,0.00008687568,0.00003123908,0.000006354697,0.00008564487,0.00002981659,0.0001030712,0.9976376,0.0003342857,0.00005149305,0.001461143],"study_design_scores_gemma":[0.0000153365,0.0002907619,0.0003547889,0.000003626765,0.000006616124,0.0001693328,0.000008279388,0.0001762696,0.9969822,0.00004596694,0.00194206,0.000004741602],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886355,0.0006007251,0.004202672,0.00009109065,0.00005049628,0.00004867099,0.00009511458,0.00009564899,0.006180006],"genre_scores_gemma":[0.9939317,0.0002785118,0.001473252,0.00003549025,0.000008394358,0.00001203457,0.00009966156,0.00001278401,0.004148234],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002434628,"threshold_uncertainty_score":0.008144677,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05554742395166022,"score_gpt":0.3632724269409544,"score_spread":0.3077250029892942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}