{"id":"W4295277348","doi":"10.1016/j.carres.2022.108674","title":"One-pot expeditious synthesis of glycosylated esters through activation of carboxylic acids using trichloroacetonitrile","year":2022,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Banaras Hindu University; Council of Scientific and Industrial Research, India; Science and Engineering Research Board; Canadian Institute of Steel Construction","keywords":"Chemistry; Synthon; Yield (engineering); Glycosylation; Reaction conditions; Organic chemistry; Combinatorial chemistry; Substrate (aquarium); Catalysis; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005655017,0.001371673,0.0006303843,0.0005630916,0.0004874258,0.000328454,0.0008832141,0.0006497434,0.003163924],"category_scores_gemma":[0.0003384886,0.0002732508,0.0005213972,0.0008481999,0.0003416738,0.0007169713,0.0008985364,0.00119997,0.002340665],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005333115,"about_ca_system_score_gemma":0.001682544,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001657978,"about_ca_topic_score_gemma":0.002952512,"domain_scores_codex":[0.9996548,0.00004114081,0.00002988551,0.00004980612,0.00005171042,0.0001726328],"domain_scores_gemma":[0.9998591,0.00001998431,0.00002334262,0.00002313205,0.00002923663,0.00004520134],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004969059,0.000367826,0.0002973276,0.0009309739,0.00009173043,0.001289113,0.0003453623,0.001488894,0.9511932,0.003303932,0.001762456,0.03843235],"study_design_scores_gemma":[0.00006121324,0.0004592372,0.0005645426,0.00002663371,0.00003437099,0.000462097,0.00006207114,0.0007236348,0.9856162,0.0003801855,0.01156416,0.00004564765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.794907,0.007467551,0.1357664,0.001159228,0.0006223668,0.001168077,0.002563502,0.001346207,0.05499962],"genre_scores_gemma":[0.9593933,0.005715611,0.02052722,0.0002420258,0.00005091869,0.0002810629,0.001097815,0.0001534714,0.01253857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003163924,"threshold_uncertainty_score":0.01058441,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1103065801030549,"score_gpt":0.33434678479112,"score_spread":0.224040204688065,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}