{"id":"W4295780359","doi":"10.1021/acscatal.2c01852","title":"Kinetic Coupling of Redox and Acid Chemistry in Methanol Partial Oxidation on Vanadium Oxide Catalysts","year":2022,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University; University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Suncor Energy Incorporated","keywords":"Dehydrogenation; Chemistry; Catalysis; Catalytic cycle; Dimethoxymethane; Methanol; Inorganic chemistry; Photochemistry; Vanadium; Bond cleavage; Lewis acids and bases; Vanadium oxide; Partial oxidation; Redox; Methyl formate; Formaldehyde; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002376828,0.0001431879,0.0002858232,0.0001986144,0.00008626292,0.0000139882,0.000163593,0.00005800891,0.0001736785],"category_scores_gemma":[0.0001614139,0.0001635688,0.00009295979,0.0007282122,0.00003275022,0.00009358501,0.0001247535,0.0002434336,0.000007612136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00015335,"about_ca_system_score_gemma":0.00002619615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004814199,"about_ca_topic_score_gemma":0.00004577895,"domain_scores_codex":[0.9987571,0.00001053904,0.0004067205,0.0003303188,0.0003037263,0.0001916269],"domain_scores_gemma":[0.9992332,0.0000958029,0.0001574041,0.0003994051,0.00003832992,0.00007586269],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001856507,0.00007972991,0.0003505547,0.00003205918,0.00007175331,0.000004414154,0.0001364352,0.03049689,0.9681973,0.00005869218,0.00008605774,0.0004675173],"study_design_scores_gemma":[0.0003272652,0.00001134537,0.000688785,0.00001175471,0.0001318697,0.000006519625,0.0002769675,0.01847153,0.9791435,0.00001574221,0.0007531282,0.0001615817],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989515,0.0001416177,0.000296067,0.0001564026,0.00003651656,0.00008477603,0.00003551219,0.00003709196,0.0002605168],"genre_scores_gemma":[0.9986512,0.00002016905,0.00007631386,0.0000273321,0.0000319871,0.00008359941,0.0007934648,0.00002070243,0.0002952],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01202536,"threshold_uncertainty_score":0.6670141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00871992643775356,"score_gpt":0.2241235118448667,"score_spread":0.2154035854071131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}