{"id":"W4295905570","doi":"10.1021/acs.analchem.2c02643","title":"Real-Time Convolutional Voltammetry Enhanced by Energetic (Hot) Electrons and Holes on a Surface Plasmon Waveguide Electrode","year":2022,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Cyclic voltammetry; Analytical Chemistry (journal); Surface plasmon; Chronoamperometry; Electrode; Plasmon; Molecular physics; Optoelectronics; Electrochemistry; Materials science; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001439577,0.0003416223,0.0004228643,0.00002657042,0.0004067679,0.00004577438,0.0003678776,0.0001622154,0.003389278],"category_scores_gemma":[0.00008584837,0.0003582221,0.0001796975,0.0004245147,0.0001835049,0.00003668851,0.0001635329,0.0007500522,0.00004592573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003674051,"about_ca_system_score_gemma":0.0001242406,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004256504,"about_ca_topic_score_gemma":0.000001005092,"domain_scores_codex":[0.9974508,0.00002429955,0.0004421107,0.0008220811,0.0005698896,0.0006908239],"domain_scores_gemma":[0.998745,0.0002936845,0.0001406062,0.0004588833,0.00005836165,0.0003034454],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008503089,0.0003054118,0.00006125586,0.00003335382,0.0001520397,0.000002629985,0.00000762695,0.0001303841,0.985553,0.0007025718,0.0128958,0.0000709375],"study_design_scores_gemma":[0.0003774565,0.00004777817,0.000009127916,0.00000995135,0.0001534575,0.00001474767,0.00003362481,0.02126152,0.9702578,0.0007694203,0.006667666,0.0003974895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9637436,0.0002213414,0.0001302759,0.0007060104,0.000003833789,0.0000444388,0.0001237207,0.0001295359,0.0348972],"genre_scores_gemma":[0.9777552,0.0001607238,0.00009150881,0.0001795161,0.00009415188,0.00007023275,0.0007637553,0.00004133305,0.02084358],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02113113,"threshold_uncertainty_score":0.999887,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003872842228250256,"score_gpt":0.2139720981144184,"score_spread":0.2100992558861682,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}