{"id":"W4296037859","doi":"10.1039/d2dt02519a","title":"Coordination chemistry and structural rearrangements of the Me<sub>2</sub>PCH<sub>2</sub>AlMe<sub>2</sub>ambiphilic ligand","year":2022,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Phosphine; Rhodium; Ligand (biochemistry); Medicinal chemistry; Chloride; Substituent; Toluene; Iridium; Benzene; Cyclooctadiene; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006241779,0.0002386302,0.00008684015,0.0000895444,0.0001942645,0.0003168819,0.0002381222,0.0001842118,0.002597203],"category_scores_gemma":[0.0001408459,0.0001142253,0.00007169961,0.00008338584,0.0002753707,0.0002104139,0.0002761097,0.000349158,0.0003118264],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002386343,"about_ca_system_score_gemma":0.0001360849,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005010479,"about_ca_topic_score_gemma":0.0008750733,"domain_scores_codex":[0.9999524,0.00000791048,0.000002488773,0.00001114,0.00001073878,0.0000153167],"domain_scores_gemma":[0.9999715,0.000007228227,0.000006689482,0.00000428427,0.000003974014,0.000006412215],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002636713,0.00001897811,0.0002992858,0.00007764167,0.000007003001,0.0001536265,0.000139489,0.0005640674,0.9892308,0.00292995,0.000224819,0.006090752],"study_design_scores_gemma":[0.00001582242,0.000142389,0.00101145,0.000003240909,0.00000648808,0.0001826173,0.00007107007,0.0007256648,0.9937155,0.0003302892,0.003786628,0.000008749536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870869,0.0005059359,0.003018108,0.000101525,0.00002050772,0.00002267774,0.0001024681,0.0001134817,0.009028388],"genre_scores_gemma":[0.997012,0.0001898744,0.0007364299,0.00003129267,0.000003483004,0.00001044636,0.00005279942,0.0000128365,0.001950895],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002597203,"threshold_uncertainty_score":0.008688569,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008486296160341647,"score_gpt":0.2038589240187473,"score_spread":0.1953726278584056,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}