{"id":"W4296624871","doi":"10.1002/slct.202202601","title":"Spectra of CO<sub>2</sub>‐Kr in the 4.3 μm region: Intermolecular Bend and Symmetry Breaking of the Intramolecular CO<sub>2</sub> Bend","year":2022,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Intramolecular force; Intermolecular force; Infrared; Chemistry; Atomic physics; Infrared spectroscopy; Isotopic shift; Spectral line; Absorption spectroscopy; Scaling; Absorption (acoustics); Kinetic isotope effect; Molecular physics; Deuterium; Physics; Molecule; Optics; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000875945,0.0002285093,0.0001889298,0.0002955052,0.0002640424,0.000170095,0.0003955412,0.0003367507,0.003412563],"category_scores_gemma":[0.0001688946,0.0001078672,0.000113124,0.000233399,0.0002829806,0.0002536222,0.0001983299,0.000554906,0.0002368788],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003287569,"about_ca_system_score_gemma":0.00008597015,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007458112,"about_ca_topic_score_gemma":0.0006582842,"domain_scores_codex":[0.9999204,0.000005412563,0.000001190429,0.000018118,0.00003263599,0.00002219312],"domain_scores_gemma":[0.9997639,0.0000876007,0.00006495172,0.00001410785,0.00003233976,0.00003716835],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002642529,0.00002567898,0.001081146,0.00004220006,0.00001083074,0.0001385941,0.0000824558,0.0002717213,0.9959948,0.0002003327,0.00015414,0.001733854],"study_design_scores_gemma":[0.00003444338,0.0004331304,0.04296096,0.00001384997,0.00002924273,0.0004728613,0.0001926418,0.005671429,0.9484971,0.0001689542,0.001500583,0.00002476885],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964752,0.0002053651,0.001078899,0.00006726469,0.000006948755,0.000002379159,0.00009590768,0.00006435836,0.002003778],"genre_scores_gemma":[0.9985659,0.00005470817,0.0005250334,0.00001997638,0.000003164287,0.000003029736,0.00008159162,0.00001860459,0.0007279839],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003412563,"threshold_uncertainty_score":0.0114162,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007474987062997437,"score_gpt":0.23166483764986,"score_spread":0.2241898505868626,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}