{"id":"W4301056089","doi":"10.1515/9783110668612-008","title":"Metal–ligand bonding in six-coordinate d-block complexes probed by luminescence spectroscopy at variable pressure","year":2022,"lang":"en","type":"book-chapter","venue":"","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Luminescence; Block (permutation group theory); Metal; Spectroscopy; Materials science; Ligand (biochemistry); Variable (mathematics); Chemistry; Crystallography; Optoelectronics; Physics; Metallurgy; Mathematics; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005747682,0.0006531848,0.001041216,0.000236785,0.0003872074,0.0001768016,0.000692116,0.0002185552,0.03335688],"category_scores_gemma":[0.00001777176,0.0005813286,0.000178449,0.0001410702,0.0001894194,0.0004045975,0.0004726408,0.0004572663,0.0003428761],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001622275,"about_ca_system_score_gemma":0.00008548554,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000563352,"about_ca_topic_score_gemma":0.0002468568,"domain_scores_codex":[0.9966297,0.00009128048,0.0007565038,0.001107247,0.0007543882,0.000660945],"domain_scores_gemma":[0.9987375,0.0001082981,0.0003374786,0.0005949551,0.00007587801,0.0001458842],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00008965136,0.00005038378,0.00002389405,0.0001893637,0.00004897209,0.00004626325,0.00005380967,0.00002113987,0.7660576,0.2215838,0.01183239,0.000002768011],"study_design_scores_gemma":[0.0006534631,0.0001506516,0.00001220485,0.0001345745,0.0002047223,0.00006739932,0.0000129058,0.00004355615,0.4775872,0.01285319,0.5074859,0.0007942222],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.01812826,0.003413143,0.000249426,0.000674269,0.001220686,0.00203023,0.002283111,0.0005386278,0.9714622],"genre_scores_gemma":[0.08813577,0.0001129811,0.003371641,0.0003050188,0.0001268829,0.00009709534,0.0004981552,0.0001310967,0.9072214],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.4956535,"threshold_uncertainty_score":0.9996638,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0158983002114849,"score_gpt":0.2290877574767144,"score_spread":0.2131894572652295,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}