{"id":"W4302276310","doi":"10.1039/d2cp02682a","title":"Taking a different road: following Ag<sub>25</sub> and Au<sub>25</sub> cluster activation <i>via in situ</i> differential pair distribution function analysis","year":2022,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Canada Foundation for Innovation; University of Saskatchewan; Canadian Light Source","keywords":"Extended X-ray absorption fine structure; Cluster (spacecraft); Crystallography; Metal; Analytical Chemistry (journal); Particle size; Coalescence (physics); Pair distribution function; Materials science; Crystal structure; Chemistry; Particle (ecology); Absorption spectroscopy; Physical chemistry; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001345925,0.0002678516,0.0002443129,0.0003080757,0.0002563222,0.0005323666,0.0004513281,0.0003162071,0.00229235],"category_scores_gemma":[0.0002668399,0.000142721,0.0002148675,0.0002655868,0.0004323509,0.0004332597,0.0002283292,0.0007068621,0.0005577711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005020605,"about_ca_system_score_gemma":0.0001715945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00101629,"about_ca_topic_score_gemma":0.001924645,"domain_scores_codex":[0.9998701,0.000006416543,0.000004036818,0.00004948171,0.00004352066,0.00002643874],"domain_scores_gemma":[0.9998786,0.00002034849,0.00003907798,0.00001493353,0.00003576858,0.00001123828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000806369,0.00001164383,0.0009643701,0.00007909277,0.0000161933,0.00008515784,0.0001383152,0.0002773921,0.989693,0.0008824242,0.0003951683,0.007376633],"study_design_scores_gemma":[0.000002285366,0.00005643647,0.003307413,0.000003252062,0.00001162515,0.0001061569,0.00007746314,0.002692154,0.9911848,0.0002927326,0.002253677,0.00001211666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9600304,0.0005387492,0.03253813,0.0003790401,0.00008978196,0.00002930312,0.0007172545,0.0008737299,0.004803597],"genre_scores_gemma":[0.9815602,0.0003739701,0.01282701,0.0001836282,0.0000141841,0.00003070952,0.0003911664,0.0001514823,0.004467666],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00229235,"threshold_uncertainty_score":0.007668614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00979703223731062,"score_gpt":0.2211557499181468,"score_spread":0.2113587176808362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}