{"id":"W4306398769","doi":"10.3390/pr10102094","title":"An Intensified Green Process for the Coproduction of DMC and DMO by the Oxidative Carbonylation of Methanol","year":2022,"lang":"en","type":"article","venue":"Processes","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"King Saud University","keywords":"Dimethyl carbonate; Methanol; Environmentally friendly; Process engineering; Renewable energy; Chemistry; Carbonylation; Pulp and paper industry; Environmental science; Waste management; Organic chemistry; Catalysis; Engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000266336,0.00008122923,0.0001415114,0.00004490284,0.00009063067,0.000007325562,0.0001935125,0.00002283646,0.00002148378],"category_scores_gemma":[0.0006883515,0.00005568915,0.00002618458,0.0005359063,0.00009132494,0.0001107995,0.00004557705,0.00008274092,5.891761e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002092243,"about_ca_system_score_gemma":0.00004041341,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000121527,"about_ca_topic_score_gemma":0.00001623709,"domain_scores_codex":[0.9992763,0.00002272677,0.0002206176,0.0001781488,0.0002214833,0.0000807553],"domain_scores_gemma":[0.9987982,0.0003283315,0.0001942056,0.0002019635,0.0004614897,0.00001580449],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002825438,0.0001626857,0.001537169,0.003084726,0.0003145544,1.015194e-7,0.01464081,0.05160354,0.9202887,0.0005356969,0.000296912,0.007252532],"study_design_scores_gemma":[0.0002139595,0.00005673689,0.00006003212,0.0000112222,0.000127807,0.000003086215,0.004649716,0.04959998,0.9440262,0.0006122115,0.0005557886,0.00008328525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9691842,0.004346456,0.02397268,0.001039252,0.0001167585,0.0009235561,0.0001850601,0.00008483452,0.0001471748],"genre_scores_gemma":[0.9994067,0.00003539104,0.00006188473,0.00002689647,0.00003323927,0.0002797874,0.00005507946,0.0000161363,0.00008487835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03022248,"threshold_uncertainty_score":0.2270938,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02280008241714566,"score_gpt":0.281213610715241,"score_spread":0.2584135282980954,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}