{"id":"W4306848269","doi":"10.1002/jccs.202200404","title":"Collaborative control of branching ratio in the O + <scp>HO<sub>2</sub></scp> → <scp>OH</scp> + <scp>O<sub>2</sub></scp> reaction via vibrational and rotational excitation","year":2022,"lang":"en","type":"article","venue":"Journal of the Chinese Chemical Society","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Natural Science Foundation of China","keywords":"Chemistry; Excitation; Branching fraction; Branching (polymer chemistry); Reaction dynamics; Atomic physics; Potential energy surface; Work (physics); Analytical Chemistry (journal); Molecule; Physics; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001701115,0.0003369726,0.0005120306,0.00003811377,0.0006651142,0.0001425484,0.0005172415,0.0001739346,0.00001800946],"category_scores_gemma":[0.001559894,0.0002212734,0.0004173358,0.00122595,0.000257282,0.0008105567,0.00006559936,0.001081258,0.000005718223],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008662861,"about_ca_system_score_gemma":0.0002965956,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003578335,"about_ca_topic_score_gemma":0.00005168186,"domain_scores_codex":[0.9964476,0.0005162485,0.0009555045,0.0003292781,0.0013425,0.0004089241],"domain_scores_gemma":[0.9937297,0.004297378,0.001290354,0.0002027363,0.0003282872,0.0001515151],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00003633208,0.0002036345,0.07339911,0.00005744725,0.0002364149,0.000008730382,0.0127184,0.01507634,0.8911613,0.00007782145,0.005742342,0.001282167],"study_design_scores_gemma":[0.004661673,0.000448511,0.7658008,0.00009968092,0.0002606199,0.0004011879,0.01967659,0.0554899,0.1345278,0.01718066,0.001302835,0.0001497034],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954633,0.0008192736,0.001538548,0.0007384951,0.0004190949,0.0004226858,0.0001634102,0.00001679947,0.0004184324],"genre_scores_gemma":[0.9972847,0.0002466298,0.0005956371,0.001176515,0.0005180555,0.00001590724,0.00012904,0.00001640571,0.0000171625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7566334,"threshold_uncertainty_score":0.9023268,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00472718010666956,"score_gpt":0.2022423371717133,"score_spread":0.1975151570650437,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}