{"id":"W4306867616","doi":"10.1002/cjce.24729","title":"Production of <scp>NMSBA</scp> from the oxidation of <scp>NMST</scp> in the homogeneous <scp> Co/Mn/Br/H <sub>3</sub> PMo <sub> <i>x</i> </sub> W <sub> 12− <i>x</i> </sub> O <sub>40</sub> </scp> catalytic system","year":2022,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Oxidizing agent; Catalysis; Acetic acid; Yield (engineering); Chemistry; Homogeneous; Oxygen; Nitric acid; Nuclear chemistry; Inorganic chemistry; Materials science; Organic chemistry; Metallurgy","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.003922272,0.0009038917,0.001361148,0.0006540543,0.0008050607,0.0003296945,0.002758743,0.0003773466,0.000007111673],"category_scores_gemma":[0.002975503,0.0007100057,0.0006521029,0.001929988,0.0006095396,0.0005850634,0.0002786508,0.001628354,0.00005317894],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001072321,"about_ca_system_score_gemma":0.001236011,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008256289,"about_ca_topic_score_gemma":0.0006316194,"domain_scores_codex":[0.9927839,0.0005459605,0.002348394,0.0009284845,0.001775968,0.001617286],"domain_scores_gemma":[0.9921361,0.003030002,0.001842375,0.001650766,0.0004532314,0.0008874839],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001158016,0.0001375187,0.00007396044,0.0001900803,0.0001648466,0.00004994412,0.001964083,0.01850397,0.9739932,0.0002627237,0.003556952,0.00109113],"study_design_scores_gemma":[0.0006337139,0.0001101765,0.0005812875,0.0004379285,0.0004245342,0.0006998333,0.00123888,0.001516854,0.9919191,0.0002036809,0.002035942,0.0001980818],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937347,0.002245543,0.0003265757,0.0005344551,0.0009974221,0.001152994,0.0006884054,0.0001049449,0.0002149473],"genre_scores_gemma":[0.997952,0.0001723605,0.0001020349,0.0002859168,0.0008788159,0.0002702106,0.000132119,0.0001921334,0.00001445042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01792588,"threshold_uncertainty_score":0.9995351,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00954866842616793,"score_gpt":0.182746800743355,"score_spread":0.1731981323171871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}