{"id":"W4306893608","doi":"10.1002/ange.202213744","title":"Unexpected Formation and Potent Antioxidant Activity of Macrocyclic Dimers Containing Disulfide and Selenide Groups","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Selenide; Chemistry; Thiol; Hydrogen peroxide; Autocatalysis; Selenium; Redox; Antioxidant; Catalysis; Disulfide bond; Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001121774,0.0001982125,0.0001657812,0.0001170296,0.0001005517,0.0001353048,0.0001962292,0.0001707788,0.0007462971],"category_scores_gemma":[0.0001066471,0.00009713874,0.0001003817,0.00006761777,0.0001284784,0.00008961343,0.0001663167,0.0002213524,0.0002443528],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008915503,"about_ca_system_score_gemma":0.00008669717,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000749445,"about_ca_topic_score_gemma":0.0001595741,"domain_scores_codex":[0.9999375,0.00001399171,0.000005161464,0.0000187705,0.00001086674,0.00001367093],"domain_scores_gemma":[0.9999441,0.000005871405,0.00001467561,0.000008392356,0.000007847808,0.00001910335],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006777769,0.00001467894,0.0001485501,0.00002349872,0.00000907802,0.00008366857,0.00002057211,0.0001039559,0.997263,0.0001253936,0.00005346374,0.002086449],"study_design_scores_gemma":[0.00001411922,0.0007059427,0.0008651,0.000003165487,0.00001044635,0.0001940536,0.00001254386,0.0003180764,0.9952058,0.00004533303,0.002620559,0.00000486137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993766,0.001250719,0.002676533,0.0000681087,0.00002201999,0.00002765547,0.0001412098,0.00005865763,0.001989116],"genre_scores_gemma":[0.9968525,0.0003383679,0.001382385,0.0000272218,0.000005946993,0.00001535171,0.0001120554,0.000005563745,0.001260672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007462971,"threshold_uncertainty_score":0.00249666,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0410682766177145,"score_gpt":0.3291512452505937,"score_spread":0.2880829686328792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}