{"id":"W4307299354","doi":"10.1002/ange.202213462","title":"Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Division of Chemistry; Office of Research and Economic Development, Montana State University","keywords":"Disproportionation; Chemistry; Bimetallic strip; Catalysis; Nickel; Hydrazine (antidepressant); Catalytic cycle; Medicinal chemistry; Ammonia; Ligand (biochemistry); Inorganic chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009078456,0.0002303048,0.0001933477,0.00008831926,0.0002086466,0.0003068902,0.0004946087,0.0002990213,0.0009549009],"category_scores_gemma":[0.0001115925,0.00007729846,0.00009392602,0.00007149301,0.0001652042,0.000163331,0.0003541368,0.0002176984,0.0003413788],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005126162,"about_ca_system_score_gemma":0.0002107269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001050075,"about_ca_topic_score_gemma":0.001794484,"domain_scores_codex":[0.9998486,0.00001775422,0.000007543887,0.00003307805,0.00006277919,0.0000301729],"domain_scores_gemma":[0.9999764,0.000002371791,0.00000472056,0.000003211783,0.00000536998,0.000007926143],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009493983,0.0000643727,0.0002487615,0.0002107148,0.00002292508,0.0002007819,0.0001142065,0.0002554205,0.9920315,0.001675438,0.0009623918,0.004118572],"study_design_scores_gemma":[0.00003528499,0.0001657516,0.0006065954,0.000009983894,0.00002197151,0.0002677281,0.00004145504,0.001685132,0.9814943,0.0001350587,0.01552153,0.00001506217],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.961544,0.001992229,0.007106894,0.0003948095,0.0001860235,0.00007045467,0.0001848344,0.0002796663,0.02824104],"genre_scores_gemma":[0.9926639,0.0003503191,0.0015861,0.00003605449,0.000009802864,0.00001567172,0.0001291964,0.00001914909,0.005189913],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001050075,"threshold_uncertainty_score":0.00371927,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02138172176123758,"score_gpt":0.2385919649387354,"score_spread":0.2172102431774978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}