{"id":"W4307299354","doi":"10.1002/ange.202213462","title":"Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Division of Chemistry; Office of Research and Economic Development, Montana State University","keywords":"Disproportionation; Chemistry; Bimetallic strip; Catalysis; Nickel; Hydrazine (antidepressant); Catalytic cycle; Medicinal chemistry; Ammonia; Ligand (biochemistry); Inorganic chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001247417,0.0001743457,0.0002021635,0.00006360643,0.000201545,0.00002336175,0.0002425825,0.00004586374,0.000730868],"category_scores_gemma":[0.00004764123,0.0001916636,0.0001003074,0.00030432,0.00002099792,0.00007782208,0.0001708089,0.0001775831,0.0001559301],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00027004,"about_ca_system_score_gemma":0.0000217879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001391186,"about_ca_topic_score_gemma":0.00000470985,"domain_scores_codex":[0.9988138,0.00001664862,0.0002280397,0.0003245402,0.00029792,0.0003190307],"domain_scores_gemma":[0.9994217,0.00004260655,0.00006319494,0.0002869686,0.00003020333,0.0001553581],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003097712,0.00006681484,0.00009372038,0.00001216308,0.00004026643,0.000002663173,0.0001465539,0.000107809,0.956052,0.00007315021,0.04263777,0.0007361126],"study_design_scores_gemma":[0.0002268459,0.00002986482,0.00005871499,0.000004477886,0.00003132355,0.00001645762,0.0001794672,0.0002305748,0.9126585,0.00003200131,0.08631283,0.0002189618],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948195,0.0003342924,0.0005288975,0.0009016814,0.0001188993,0.0002147622,0.0001316753,0.0001980302,0.00275227],"genre_scores_gemma":[0.9957873,0.000006470985,0.000766796,0.0002951168,0.0001269318,0.0002006987,0.0004282174,0.00004799612,0.002340469],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04367506,"threshold_uncertainty_score":0.8002492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02138172176123758,"score_gpt":0.2385919649387354,"score_spread":0.2172102431774978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}