{"id":"W4308444807","doi":"10.26434/chemrxiv-2022-w9qvx-v2","title":"Planar Bismuth Triamides: A Tunable Platform for Main Group Lewis Acidity and Polymerization Catalysis","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; Western University; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University; York University","keywords":"Chemistry; Lewis acids and bases; Bismuth; Catalysis; Polymerization; Steric effects; Ligand (biochemistry); Polymer chemistry; Computational chemistry; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006755481,0.0003042917,0.0001787714,0.0001546076,0.00009268758,0.0002959975,0.0003107156,0.0002449308,0.0009109327],"category_scores_gemma":[0.00009711013,0.0001548977,0.0001555617,0.0001258333,0.0001953654,0.0002428887,0.0003023553,0.0003352434,0.000357299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000226457,"about_ca_system_score_gemma":0.00009868731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002296669,"about_ca_topic_score_gemma":0.0004202774,"domain_scores_codex":[0.9999386,0.000008471985,0.000003182389,0.00001301819,0.00002170875,0.00001494377],"domain_scores_gemma":[0.9999691,0.000005280591,0.00001021892,0.000003261734,0.000004701163,0.000007379397],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000529526,0.00001516033,0.00009473677,0.00006766085,0.0000106973,0.00004365647,0.00001320756,0.0008588316,0.9935445,0.0008535036,0.00009284452,0.004352354],"study_design_scores_gemma":[0.00001710558,0.0002872446,0.0003684838,0.000005077333,0.00001404537,0.0001953713,0.00001669097,0.00318377,0.9908978,0.0001847089,0.00481808,0.00001152651],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747171,0.001996187,0.01702367,0.0001211496,0.00003399837,0.0000610592,0.0001515354,0.0002928252,0.005602431],"genre_scores_gemma":[0.9886932,0.0009223801,0.008493596,0.00004198432,0.000008002234,0.0000282394,0.0001379575,0.00003244504,0.00164212],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009109327,"threshold_uncertainty_score":0.003047407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02125398734536202,"score_gpt":0.2450700874830662,"score_spread":0.2238161001377042,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}