{"id":"W4309370217","doi":"10.1016/j.tetlet.2022.154242","title":"Palladium catalyzed amidation of phenyl carboxylates and anilines using aqueous micellar catalysis","year":2022,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"Paraza Pharma (Canada)","funders":"","keywords":"Chemistry; Catalysis; Palladium; Stoichiometry; Aqueous solution; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001178473,0.0001208225,0.000186845,0.00005922991,0.00009646719,0.00001166081,0.0001266389,0.00004118929,0.00004979262],"category_scores_gemma":[0.00002933069,0.0001232448,0.0001091853,0.0001489661,0.00007261452,0.000003129254,0.0001211159,0.00006125302,4.596987e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003030288,"about_ca_system_score_gemma":0.00001496459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004347985,"about_ca_topic_score_gemma":0.00002141506,"domain_scores_codex":[0.9991609,0.00004595405,0.0002112961,0.0002860001,0.0001434243,0.0001524184],"domain_scores_gemma":[0.9995764,0.00001745525,0.000114937,0.0002236626,0.00002252768,0.00004499049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002319496,0.00003385146,0.004366609,0.00001827351,0.00009982224,0.000002275553,0.00004724105,0.0006301149,0.9937384,0.000001165378,0.0001182093,0.0009208842],"study_design_scores_gemma":[0.0002362139,0.00003031276,0.0004720836,0.000004168394,0.0001523767,0.00001097166,0.0001190856,0.001511218,0.995925,0.000006191553,0.001351298,0.0001810703],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984049,0.0009979729,0.0001335241,0.0003085968,0.00003269011,0.00005909966,0.00002779023,0.000007817915,0.00002757311],"genre_scores_gemma":[0.9990495,0.00004745675,0.0003031178,0.0002218425,0.00007736754,0.000006376055,0.0002507622,0.0000164201,0.00002715783],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003894526,"threshold_uncertainty_score":0.5025776,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007030709584742713,"score_gpt":0.2110662237384591,"score_spread":0.2040355141537163,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}