{"id":"W4309544270","doi":"10.1016/j.jms.2022.111718","title":"Synchrotron-based infrared spectroscopy of the Coriolis perturbed ν6 and ν8 bands of trans-DCOOH","year":2022,"lang":"en","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Light Source (Canada)","funders":"Western Economic Diversification Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; University of Adelaide; National Research Council Canada; Canada Foundation for Innovation; University of Saskatchewan; National Science Foundation","keywords":"Infrared; Physics; Synchrotron radiation; Synchrotron; Resolution (logic); Spectral line; Infrared spectroscopy; Spectroscopy; Atomic physics; Nuclear magnetic resonance; Analytical Chemistry (journal); Optics; Chemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001406589,0.000210161,0.0005470245,0.00007562277,0.0001427185,0.00001180936,0.0003904637,0.00002376191,0.000151915],"category_scores_gemma":[0.00001690608,0.0001648224,0.0003794848,0.0002895852,0.0002090662,0.0000700057,0.0001139286,0.0005034551,1.608516e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008636635,"about_ca_system_score_gemma":0.0001719126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001576237,"about_ca_topic_score_gemma":3.419996e-7,"domain_scores_codex":[0.9983985,0.00009339531,0.0005513587,0.0001708197,0.0005287745,0.0002571806],"domain_scores_gemma":[0.998656,0.00009348452,0.0007529253,0.0002921529,0.0001295955,0.00007581738],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002069801,0.0002191763,0.003776472,0.00002962277,0.000209666,0.000004449201,0.0002449221,0.002179466,0.9913099,0.001396116,0.0003448986,0.00007827186],"study_design_scores_gemma":[0.001443623,0.0004771334,0.0006008156,0.00004930529,0.0001397607,0.000003822588,0.0002780816,0.0001226794,0.9711215,0.02513599,0.0004825021,0.000144775],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9801835,0.0008063205,0.01615893,0.0004048109,0.0001790248,0.0001875789,0.00007370311,0.000005047728,0.002001035],"genre_scores_gemma":[0.9957829,0.00001374669,0.003928577,0.00008527919,0.0001166642,0.000008738358,0.000003611317,0.00002847043,0.00003208303],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02373988,"threshold_uncertainty_score":0.6721264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003824422247445178,"score_gpt":0.2279918536244459,"score_spread":0.2241674313770007,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}