{"id":"W4309760816","doi":"10.1021/acs.macromol.2c01078","title":"Ultrafast Derived Self-Healable, Reprocessable Polyurethane Elastomer Based on Dynamic “Electrophilic Substitution (ES)-Click” Chemistry","year":2022,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Science and Engineering Research Board; Natural Sciences and Engineering Research Council of Canada","keywords":"Prepolymer; Click chemistry; Ultimate tensile strength; Polymer chemistry; Polyurethane; Materials science; Isocyanate; Polymer; Differential scanning calorimetry; Contact angle; Chemical engineering; Chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001179755,0.0002964914,0.0001145146,0.0001101544,0.00005519239,0.0001223942,0.0001386984,0.0002144833,0.0007441744],"category_scores_gemma":[0.0001447449,0.0001263462,0.0001984378,0.00007667189,0.0001301616,0.0003161176,0.0001643366,0.0003147763,0.0002399832],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008283226,"about_ca_system_score_gemma":0.00007471031,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007127097,"about_ca_topic_score_gemma":0.0001370902,"domain_scores_codex":[0.9999233,0.000008052722,0.000006652693,0.00002177987,0.00002270152,0.00001754491],"domain_scores_gemma":[0.9998995,0.00001576777,0.00004159449,0.0000130448,0.00001358891,0.000016436],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001546487,0.000006858817,0.0000461506,0.00002318123,0.000002132785,0.00003244487,0.000007537644,0.00006027806,0.9979355,0.00009634777,0.00001945261,0.001754609],"study_design_scores_gemma":[0.000002160567,0.00008798057,0.0004418094,0.000001387325,0.000003352639,0.0001293243,0.000003149747,0.0005865425,0.9977897,0.00001365525,0.0009368401,0.000004119595],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9734622,0.001073514,0.02341781,0.00004842362,0.00004050303,0.00003152827,0.0001189022,0.0002455117,0.001561583],"genre_scores_gemma":[0.9857642,0.0004777933,0.01177907,0.00003582964,0.00001009986,0.00002914185,0.0001261734,0.00002006373,0.001757458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007441744,"threshold_uncertainty_score":0.002489448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005111144083358343,"score_gpt":0.2141572593390998,"score_spread":0.2090461152557415,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}