{"id":"W4309760816","doi":"10.1021/acs.macromol.2c01078","title":"Ultrafast Derived Self-Healable, Reprocessable Polyurethane Elastomer Based on Dynamic “Electrophilic Substitution (ES)-Click” Chemistry","year":2022,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Science and Engineering Research Board; Natural Sciences and Engineering Research Council of Canada","keywords":"Prepolymer; Click chemistry; Ultimate tensile strength; Polymer chemistry; Polyurethane; Materials science; Isocyanate; Polymer; Differential scanning calorimetry; Contact angle; Chemical engineering; Chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004185285,0.0003426699,0.0003384768,0.0001156842,0.000902308,0.0001401968,0.0005745203,0.00009574102,0.001395722],"category_scores_gemma":[0.00003847119,0.000363661,0.0001262533,0.0005589731,0.0000998942,0.0001101913,0.0001373568,0.0003989627,0.0001158649],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003789382,"about_ca_system_score_gemma":0.0002719731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000156068,"about_ca_topic_score_gemma":0.000008423938,"domain_scores_codex":[0.9970824,0.000182201,0.000410717,0.0008370954,0.000664982,0.0008225703],"domain_scores_gemma":[0.9988109,0.00008102075,0.0002172406,0.0006357428,0.00006462885,0.0001904195],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001952474,0.0002878085,0.00009270479,0.00009141202,0.00001356801,0.00007229227,0.0001054757,0.008506691,0.9904162,0.00007886865,0.00005170131,0.00008802745],"study_design_scores_gemma":[0.000766264,0.0002304158,0.0001877237,0.00002896272,0.00004027896,0.0001278617,0.00005230343,0.03403801,0.9626332,0.00007716606,0.001383364,0.0004344746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948184,0.000571997,0.001669051,0.0005279375,0.0002634333,0.000249366,0.0001019789,0.0004758704,0.001321926],"genre_scores_gemma":[0.9972939,0.00002343324,0.00105086,0.0009749629,0.00006968393,0.0001226961,0.0001571181,0.00005752394,0.0002497741],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02778303,"threshold_uncertainty_score":0.9998815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005111144083358343,"score_gpt":0.2141572593390998,"score_spread":0.2090461152557415,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}