{"id":"W4309812350","doi":"10.1149/ma2022-02552064mtgabs","title":"The Transition (vs ΔpK<sub>a</sub>) from Triple Ions to Free Cations in Poor Protic Ionic Liquids Made from Weak Acids","year":2022,"lang":"en","type":"article","venue":"ECS Meeting Abstracts","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"","keywords":"Chemistry; Ion; Ionization; Cationic polymerization; Ionic bonding; Amine gas treating; Stoichiometry; Ionic liquid; Inorganic chemistry; Base (topology); Weak base; Physical chemistry; Computational chemistry; Chemical physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001259681,0.0001922066,0.0001226967,0.0003944267,0.0002310991,0.0005106815,0.0005331112,0.0004325212,0.004450712],"category_scores_gemma":[0.0007835758,0.0001948397,0.0001147466,0.0002487406,0.000673658,0.0007292284,0.0003343152,0.0008541963,0.0008945893],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002622243,"about_ca_system_score_gemma":0.0002239611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006447619,"about_ca_topic_score_gemma":0.0005776176,"domain_scores_codex":[0.9999101,0.000009428604,0.000004245131,0.00002583274,0.00002486235,0.00002539773],"domain_scores_gemma":[0.9995356,0.0002766103,0.00009192183,0.00001857404,0.00003672025,0.00004075242],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001104389,0.0001230531,0.002446684,0.0003398999,0.00002307033,0.0005050804,0.0006387556,0.001356939,0.9761392,0.002679777,0.001123747,0.01351933],"study_design_scores_gemma":[0.00002924331,0.0005582094,0.01615213,0.00006899454,0.00001845695,0.0005004779,0.0003979198,0.01032996,0.9674867,0.001657614,0.002766617,0.00003361384],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889948,0.001146714,0.00224052,0.0003757611,0.00005840691,0.0000288194,0.0006089934,0.0006558676,0.005890257],"genre_scores_gemma":[0.9980938,0.0002602222,0.0004985844,0.00007118972,0.000006237728,0.00001883173,0.00008404181,0.00002307604,0.0009439916],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004450712,"threshold_uncertainty_score":0.01488912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01106255088286582,"score_gpt":0.2129445986166887,"score_spread":0.2018820477338228,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}