{"id":"W4310720394","doi":"10.1002/chem.202203717","title":"Triple Thorpe–Ingold Effect in the Synthesis of 18‐Membered <i>C</i><sub>3</sub> Symmetric Lactams Stacking as Endless Supramolecular Tubes","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Fonds de Recherche du Québec - Santé; Natural Sciences and Engineering Research Council of Canada","keywords":"Stacking; Supramolecular chemistry; Chemistry; Crystallography; Materials science; Stereochemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008689698,0.0002104604,0.0001842675,0.00007866246,0.0001421229,0.0001672694,0.0001282364,0.0001589295,0.001101566],"category_scores_gemma":[0.0001001922,0.0001181436,0.0001341799,0.00008598778,0.0001566275,0.0002315144,0.0002226026,0.0003212588,0.0002975582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001121354,"about_ca_system_score_gemma":0.0001457999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002883957,"about_ca_topic_score_gemma":0.0006011747,"domain_scores_codex":[0.9999537,0.000005204209,0.000002181928,0.00001104871,0.000007543846,0.00002029561],"domain_scores_gemma":[0.9999639,0.000007797382,0.000008965912,0.000004184949,0.000004411748,0.00001081113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002588543,0.00006290447,0.000284082,0.0001731587,0.0000264517,0.0005010003,0.0002044912,0.001881703,0.9721843,0.003850662,0.0005184356,0.02005396],"study_design_scores_gemma":[0.0000266462,0.0006734052,0.001046916,0.00001095369,0.00001856991,0.0002279772,0.00003358343,0.002575479,0.9903468,0.000547326,0.004474882,0.0000174936],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898408,0.001072031,0.0037947,0.00006286639,0.00004264814,0.0000161669,0.0000513146,0.0000863781,0.005033136],"genre_scores_gemma":[0.9965857,0.0004161832,0.001443261,0.00002277795,0.000003815165,0.000009199113,0.00002404975,0.00001275919,0.001482187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001101566,"threshold_uncertainty_score":0.003685057,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01212202485616307,"score_gpt":0.2189117366575858,"score_spread":0.2067897118014227,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}