{"id":"W4310939967","doi":"10.1021/jacs.2c10931","title":"Ambient Temperature Carbene-Mediated Depolymerization: Stoichiometric and Catalytic Reactions of <i>N</i>-Heterocyclic- and Cyclic(Alkyl)Amino Carbenes with Poly(<i>N</i>-Methylaminoborane) [MeNH–BH<sub>2</sub>]<sub><i>n</i></sub>","year":2022,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Victoria","funders":"H2020 Marie Skłodowska-Curie Actions; Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Chemistry; Carbene; Depolymerization; Catalysis; Stoichiometry; Alkyl; Polymer chemistry; Organic chemistry; Medicinal chemistry; Photochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005332126,0.0004186821,0.0009757937,0.000171167,0.000499997,0.0001174715,0.0005512779,0.0001161762,0.000008900355],"category_scores_gemma":[0.000162833,0.0003045107,0.000313123,0.001810786,0.0009062064,0.0003432029,0.0004815888,0.0005911834,0.000001099935],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001988674,"about_ca_system_score_gemma":0.000177802,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001838913,"about_ca_topic_score_gemma":0.000006717368,"domain_scores_codex":[0.9966168,0.0003156578,0.0009745219,0.0005018151,0.001061252,0.0005299597],"domain_scores_gemma":[0.9968423,0.000348613,0.001839332,0.0004760723,0.0001711067,0.0003225842],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001975043,0.0001752159,0.0007433183,0.00009185202,0.0001614246,0.0000192118,0.0007055266,0.00008223012,0.9968003,0.000003290153,0.0002068944,0.0008132462],"study_design_scores_gemma":[0.0008796792,0.0003699272,0.00134531,0.00006087787,0.000287161,0.0006636906,0.0009453524,0.0000267797,0.9947971,0.00001550996,0.0002527942,0.0003558427],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967584,0.001691532,0.00003768897,0.0005642823,0.0003833922,0.0002819786,0.0002346841,0.00003827499,0.000009781253],"genre_scores_gemma":[0.9975262,0.0009083885,0.0003477741,0.0008531935,0.0002446343,0.00003247812,0.00002306307,0.00005977957,0.000004433864],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00200321,"threshold_uncertainty_score":0.9999407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005658021411971989,"score_gpt":0.208247862479966,"score_spread":0.202589841067994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}