{"id":"W4310939967","doi":"10.1021/jacs.2c10931","title":"Ambient Temperature Carbene-Mediated Depolymerization: Stoichiometric and Catalytic Reactions of <i>N</i>-Heterocyclic- and Cyclic(Alkyl)Amino Carbenes with Poly(<i>N</i>-Methylaminoborane) [MeNH–BH<sub>2</sub>]<sub><i>n</i></sub>","year":2022,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Victoria","funders":"H2020 Marie Skłodowska-Curie Actions; Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Chemistry; Carbene; Depolymerization; Catalysis; Stoichiometry; Alkyl; Polymer chemistry; Organic chemistry; Medicinal chemistry; Photochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001398734,0.0004548858,0.0002336062,0.0001119234,0.0001037284,0.0001732502,0.0003136389,0.0003390145,0.001095984],"category_scores_gemma":[0.000200222,0.0002041592,0.0001877928,0.0001832338,0.0002236832,0.0002709301,0.0002043553,0.0004731615,0.0002461897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002296724,"about_ca_system_score_gemma":0.0002047147,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009379667,"about_ca_topic_score_gemma":0.002058448,"domain_scores_codex":[0.9998247,0.00001834635,0.0000105132,0.00005047745,0.00004661133,0.00004940766],"domain_scores_gemma":[0.9998703,0.00002624201,0.00004629836,0.00001285611,0.00001806155,0.00002618641],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005666138,0.00001135386,0.00004556049,0.00004788237,0.000004861899,0.00001728198,0.00002176674,0.00004760617,0.998861,0.00003244821,0.0000112046,0.0008422967],"study_design_scores_gemma":[0.000004915556,0.00009980238,0.0005169361,0.000002403557,0.000004907977,0.0000259788,0.00000855924,0.0001535003,0.9988276,0.000005848975,0.0003468657,0.000002713435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925661,0.00182338,0.002584279,0.00002228084,0.00002112581,0.00004865065,0.000130495,0.00005008988,0.002753466],"genre_scores_gemma":[0.9951695,0.001154467,0.002272744,0.00002469728,0.000006442325,0.00003345361,0.0001167444,0.00002375648,0.001198251],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001095984,"threshold_uncertainty_score":0.003666401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005658021411971989,"score_gpt":0.208247862479966,"score_spread":0.202589841067994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}