{"id":"W4311203986","doi":"10.1039/d2cc05781f","title":"Facile synthesis of sulfonyl fluorides from sulfonic acids","year":2022,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada; University of British Columbia","keywords":"Sulfonyl; Chemistry; Sulfonic acid; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002395838,0.0001945916,0.0003562132,0.00007569104,0.0003073795,0.00001920165,0.002897978,0.0001194271,0.003685382],"category_scores_gemma":[0.0008640484,0.0002254194,0.0002204644,0.0002939791,0.0003792843,0.00007625224,0.00167427,0.000602492,0.00002831323],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000253293,"about_ca_system_score_gemma":0.0001099499,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002802715,"about_ca_topic_score_gemma":0.000007402124,"domain_scores_codex":[0.9984618,0.0001130642,0.0005185874,0.0003068961,0.0003481933,0.0002514354],"domain_scores_gemma":[0.9933684,0.002636986,0.0002199883,0.003598346,0.0000863338,0.00008988551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002256461,0.0003318133,0.001041304,0.00002105774,0.00006079622,7.1774e-7,0.0001592554,0.000001943772,0.9906776,0.0006917928,0.00136607,0.005625075],"study_design_scores_gemma":[0.000125467,0.000006436804,0.00004941995,0.00003503612,0.00006559951,0.000002832991,0.0005341397,0.0001451058,0.9657104,0.002075761,0.03103248,0.000217343],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9642408,0.001295416,0.00005346604,0.0009471768,0.00002181064,0.00009594195,0.001171251,0.0004393403,0.03173481],"genre_scores_gemma":[0.9901062,0.0001427015,0.008335384,0.00006083494,0.0000288616,0.0007226584,0.0003853667,0.00004333601,0.0001746256],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03156018,"threshold_uncertainty_score":0.9972254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0299059994230636,"score_gpt":0.263196288975635,"score_spread":0.2332902895525714,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}