{"id":"W4311387413","doi":"10.26434/chemrxiv-2022-cn3qd-v2","title":"Electrochemical Formation of C-S Bonds from CO2 and Small Molecule Sulfur Species","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada","keywords":"Electrosynthesis; Electrocatalyst; Chemistry; Context (archaeology); Electrochemistry; Catalysis; Molecule; Electrophile; Nanotechnology; Combinatorial chemistry; Organic chemistry; Materials science; Physical chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001516438,0.0003664232,0.0005470098,0.00009971118,0.00005654548,0.00004706691,0.0005077635,0.000459047,0.002151194],"category_scores_gemma":[0.0002447923,0.0004191934,0.00017564,0.00008975348,0.0001357216,0.00005063079,0.0008827855,0.0008367779,0.00000326127],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002562993,"about_ca_system_score_gemma":0.0001175949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007864492,"about_ca_topic_score_gemma":0.000006913872,"domain_scores_codex":[0.9982345,0.00002968644,0.0005198534,0.0005627509,0.000323295,0.0003299182],"domain_scores_gemma":[0.9983116,0.0002428184,0.0004160919,0.0008431063,0.0000847732,0.0001016281],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005249035,0.00008222228,0.0009853598,0.0004565858,0.00005764092,0.000004718696,0.0002327358,8.400524e-7,0.9970849,0.00008031023,0.0007770943,0.0001851531],"study_design_scores_gemma":[0.000207923,0.00001444482,0.0001461421,0.0001441375,0.00008863874,0.000003263984,0.0001780257,0.0001274669,0.9940926,0.001835175,0.002791368,0.0003707914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9720634,0.0009959746,0.0005070769,0.0000982062,0.00003232197,0.0001245847,0.00007163869,0.0002896485,0.0258171],"genre_scores_gemma":[0.9944463,0.0003687186,0.003277826,0.00004845053,0.0001472133,0.0001906063,0.001013918,0.00006723822,0.0004397559],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02537734,"threshold_uncertainty_score":0.999826,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0209033239261846,"score_gpt":0.2346943515595699,"score_spread":0.2137910276333853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}