{"id":"W4311449850","doi":"10.1139/cjc-2022-0256","title":"C–H arylation enables synthesis of imidazole-4-carboxamide (ICA) based fairy chemicals with plant growth-promoting activity","year":2022,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Tryptophan and brain disorders","field":"Neuroscience","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Shoot; Plant growth; Agrochemical; Imidazole; Carboxamide; Derivatization; Elongation; Rice plant; Stereochemistry; Botany; Organic chemistry; Horticulture; High-performance liquid chromatography; Biology","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001109551,0.0003265011,0.0001449228,0.0001626083,0.0001384678,0.0001197822,0.0001949131,0.0002138645,0.001223749],"category_scores_gemma":[0.0001252989,0.00007855159,0.0002176307,0.0001762416,0.0001648984,0.0002247378,0.0001970194,0.0003272494,0.000393227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002030607,"about_ca_system_score_gemma":0.0003206778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001163326,"about_ca_topic_score_gemma":0.002346337,"domain_scores_codex":[0.9999244,0.000005556546,0.000004688708,0.00001553877,0.00001155448,0.00003823016],"domain_scores_gemma":[0.9999616,0.000004498665,0.000009875431,0.00000486124,0.00000866432,0.00001038273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001319998,0.00007674272,0.0002959504,0.0002702413,0.00001597805,0.0004696869,0.0001058197,0.0006268049,0.9866093,0.0009129113,0.0003466511,0.01013803],"study_design_scores_gemma":[0.00002638672,0.0006003506,0.001545278,0.0000112631,0.00001977679,0.0002715648,0.00003477485,0.0006792037,0.9898359,0.0001443934,0.006815396,0.00001564919],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9620401,0.004137652,0.01965992,0.0002584291,0.0001210392,0.0002083054,0.0006597406,0.0002371008,0.01267775],"genre_scores_gemma":[0.9871718,0.001822519,0.007602852,0.0001001486,0.00001415053,0.00003994289,0.0002965569,0.00002223403,0.002929825],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001223749,"threshold_uncertainty_score":0.004093826,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01403490542814004,"score_gpt":0.1920696997026924,"score_spread":0.1780347942745523,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}