{"id":"W4311834077","doi":"10.48550/arxiv.2207.01522","title":"Observing the completion of the first solvation shell of carbon dioxide in argon from rotationally resolved spectra","year":2022,"lang":"en","type":"preprint","venue":"arXiv (Cornell University)","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Argon; Solvation; Spectral line; Solvation shell; Cluster (spacecraft); Chemistry; Molecule; Atomic physics; Shell (structure); Binding energy; Molecular physics; Open shell; Chemical physics; Materials science; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001354532,0.0001890559,0.0002701233,0.00006509963,0.0001095322,0.00001012737,0.0008966026,0.000179195,0.0003019346],"category_scores_gemma":[0.00005099119,0.0001656359,0.0001997696,0.0002950868,0.0001026864,0.00003259703,0.0006130866,0.000744072,3.610614e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002697974,"about_ca_system_score_gemma":0.000119563,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002801343,"about_ca_topic_score_gemma":0.00212039,"domain_scores_codex":[0.9988604,0.00009355723,0.0002876753,0.0004314723,0.0001785337,0.0001483581],"domain_scores_gemma":[0.9984629,0.0001286602,0.0005052309,0.0008144659,0.00006724049,0.00002156165],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"observational","study_design_scores_codex":[0.0003214327,0.0001088118,0.1265406,0.0003481928,0.000188765,0.00003741937,0.001252476,0.6893322,0.158144,0.02369013,0.00002063559,0.0000153301],"study_design_scores_gemma":[0.00195182,0.00004661293,0.4320462,0.0008442705,0.0004326769,0.000002166068,0.001765254,0.1149478,0.3439454,0.1025364,0.0006886867,0.0007926764],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930874,0.00008861986,0.0007797911,0.000132571,0.0001369889,0.0001786643,0.0001047906,0.00001739123,0.005473805],"genre_scores_gemma":[0.9994471,0.0000547038,0.0000911391,0.00002881619,0.00004532428,0.000001670903,0.000122619,0.00001621365,0.0001924207],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5743844,"threshold_uncertainty_score":0.6754436,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03425658470482425,"score_gpt":0.1767616076542095,"score_spread":0.1425050229493853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}