{"id":"W4311900914","doi":"10.1002/chem.202203763","title":"Cooperative Nitrile Coordination Using Nickel and a Boron‐Containing Secondary Coordination Sphere**","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Nitrile; Nickel; Boron; Coordination complex; Coordination sphere; Chemistry; Coordination number; Crystallography; Organic chemistry; Ion; Crystal structure; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001754362,0.0003624257,0.0002511212,0.0001132714,0.0001918452,0.0003597864,0.0003780074,0.000230876,0.0008272511],"category_scores_gemma":[0.0001603875,0.0001318627,0.0001015282,0.0001054311,0.0002021514,0.0002599293,0.000508677,0.0002130319,0.000396407],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003438421,"about_ca_system_score_gemma":0.000220804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005200543,"about_ca_topic_score_gemma":0.00182033,"domain_scores_codex":[0.9998758,0.00002111393,0.000008802199,0.00003697258,0.0000214297,0.00003584165],"domain_scores_gemma":[0.999931,0.0000109794,0.00001577952,0.00001675448,0.000007433948,0.00001811258],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001708117,0.00003388958,0.000342256,0.0001802431,0.00001187022,0.0001980758,0.00007944689,0.000322876,0.990033,0.002417343,0.0001938218,0.006016383],"study_design_scores_gemma":[0.00001708374,0.0002411595,0.0005034357,0.000008988553,0.000008945759,0.0003003469,0.00003112699,0.0009602921,0.9900728,0.0001346721,0.007709734,0.00001130502],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9725937,0.002042144,0.008370012,0.00009269548,0.0000330216,0.00007893379,0.0001466247,0.0001952809,0.01644751],"genre_scores_gemma":[0.9921353,0.0004612886,0.005132931,0.0000189177,0.000006340687,0.00002387327,0.0001134897,0.00001667147,0.002091218],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008272511,"threshold_uncertainty_score":0.002767444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01931785085056337,"score_gpt":0.238371565505036,"score_spread":0.2190537146544727,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}