{"id":"W4312039004","doi":"10.1039/d2dt03807b","title":"Frustrated Lewis pair-ligated tetrelenes","year":2022,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Canada Foundation for Innovation; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Alexander von Humboldt-Stiftung","keywords":"Frustrated Lewis pair; Adduct; Phosphine; Borane; Reactivity (psychology); Chemistry; Chelation; Lewis acids and bases; Methylene; Medicinal chemistry; Stereochemistry; Dissociation (chemistry); Ligand (biochemistry); Crystallography; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001359154,0.0003760628,0.0002612563,0.0001696278,0.0002725345,0.0004844421,0.0007608051,0.0003564877,0.0100226],"category_scores_gemma":[0.00015198,0.0001793918,0.0001572282,0.0002003492,0.0001902832,0.0004492848,0.0009356901,0.0005015083,0.00299728],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006694379,"about_ca_system_score_gemma":0.0002496835,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00049597,"about_ca_topic_score_gemma":0.001256368,"domain_scores_codex":[0.9998726,0.0000230826,0.000008843181,0.00002662762,0.00002729201,0.00004159535],"domain_scores_gemma":[0.9999559,0.000004231719,0.00001302465,0.00001090064,0.000006116429,0.000009876872],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009418241,0.0002382142,0.0006486275,0.0009854872,0.0001173661,0.0009990314,0.0002615139,0.002917818,0.8875547,0.05317276,0.01596635,0.03619627],"study_design_scores_gemma":[0.0002162696,0.001081546,0.0007393501,0.00004847542,0.0000441162,0.0009644341,0.0001630917,0.005965632,0.8999414,0.002788993,0.08796423,0.00008251279],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9236321,0.001126648,0.02100591,0.0007155557,0.0003171112,0.0001362754,0.001401358,0.001383069,0.05028196],"genre_scores_gemma":[0.9485362,0.0009149875,0.01602718,0.0003254893,0.0000449682,0.0001739664,0.001651358,0.0002659028,0.03206],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0100226,"threshold_uncertainty_score":0.03352898,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01281680372535329,"score_gpt":0.2248499610213857,"score_spread":0.2120331572960324,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}