{"id":"W4312079247","doi":"10.26434/chemrxiv-2022-285bs","title":"Anaerobic Hydroxylation of C(sp3)–H Bonds Enabled by the Synergistic Nature of Photoexcited Nitroarenes","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"York University","keywords":"Chemistry; Photochemistry; Hydroxylation; Hydrogen atom; Oxygen atom; Bifunctional; Oxygen; Combinatorial chemistry; Catalysis; Molecule; Organic chemistry; Enzyme","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001799427,0.0004367309,0.0001824322,0.0001433849,0.0001136776,0.0001957689,0.0002758208,0.0003208759,0.001275744],"category_scores_gemma":[0.0001136122,0.0001421193,0.0001594738,0.0001435922,0.0002544068,0.0002962668,0.0004402123,0.0006177806,0.0003465229],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000171287,"about_ca_system_score_gemma":0.0001773779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002617832,"about_ca_topic_score_gemma":0.0007277792,"domain_scores_codex":[0.9998507,0.00001385673,0.000005686552,0.00002914391,0.0000355501,0.00006496541],"domain_scores_gemma":[0.9999229,0.00001618684,0.0000230043,0.00001189938,0.00000949035,0.00001653092],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006135819,0.00002524863,0.00008250759,0.00009802758,0.000006404679,0.0001496878,0.00004927557,0.0001991666,0.9951141,0.000607109,0.0001099932,0.00349713],"study_design_scores_gemma":[0.000006087015,0.0001393351,0.0003287214,0.000003331928,0.000004489375,0.0001003255,0.0000170219,0.0005906051,0.9969111,0.00008176321,0.00181104,0.000006258492],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9795347,0.00165634,0.009501719,0.0001077083,0.00005726,0.00003596372,0.0001317903,0.000125121,0.008849367],"genre_scores_gemma":[0.9952664,0.0005415404,0.002377416,0.0000203783,0.000007647132,0.00001000275,0.00006237157,0.00001342568,0.001700786],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001275744,"threshold_uncertainty_score":0.004267812,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009814817651591257,"score_gpt":0.2512414576592122,"score_spread":0.2414266400076209,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}