{"id":"W4312079247","doi":"10.26434/chemrxiv-2022-285bs","title":"Anaerobic Hydroxylation of C(sp3)–H Bonds Enabled by the Synergistic Nature of Photoexcited Nitroarenes","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"York University","keywords":"Chemistry; Photochemistry; Hydroxylation; Hydrogen atom; Oxygen atom; Bifunctional; Oxygen; Combinatorial chemistry; Catalysis; Molecule; Organic chemistry; Enzyme","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002099695,0.0004014038,0.000662889,0.00009232459,0.0001129168,0.0000241002,0.001065805,0.000890933,0.004097306],"category_scores_gemma":[0.0007376902,0.0003391616,0.0003582124,0.0004214488,0.000352001,0.0000405186,0.0006370297,0.002572446,0.000003305601],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002611906,"about_ca_system_score_gemma":0.0001950258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003482122,"about_ca_topic_score_gemma":0.000003606714,"domain_scores_codex":[0.9976026,0.00004690962,0.0007734725,0.0006056725,0.0006549177,0.0003164074],"domain_scores_gemma":[0.9968702,0.0005992315,0.0008608661,0.001380923,0.0001679031,0.0001209387],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005735418,0.0002159148,0.0001716816,0.0007326865,0.0002220273,0.000002567547,0.00007917829,0.0004763867,0.9887004,0.0001301869,0.009146243,0.00006538801],"study_design_scores_gemma":[0.0003483219,0.00001389367,0.0001000506,0.000187703,0.0002197398,0.000002748742,0.00009613335,0.001390615,0.9882423,0.002564996,0.006519136,0.0003143912],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9796838,0.001545161,0.00002201632,0.000183187,0.0001855951,0.0002760821,0.0002020741,0.0001027447,0.01779934],"genre_scores_gemma":[0.9954082,0.00009977334,0.00008965116,0.00005908014,0.0001245023,0.0002979788,0.001535941,0.00006886408,0.002316056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01572435,"threshold_uncertainty_score":0.9999061,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009814817651591257,"score_gpt":0.2512414576592122,"score_spread":0.2414266400076209,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}