{"id":"W4312131171","doi":"10.1021/acs.jced.2c00422","title":"Expanding the Applicability Range of the Generator Column Technique to Measure the Octanol–Air Partition Ratio of Volatile Compounds","year":2022,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Toxic Organic Pollutants Impact","field":"Environmental Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"The Scarborough Hospital; University of Toronto","funders":"European Chemical Industry Council","keywords":"Chemistry; Chromatography; Octanol; Volatility (finance); Analytical Chemistry (journal); Dimensionless quantity; Partition coefficient; Volumetric flow rate; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001613748,0.001279562,0.0007771904,0.0008218662,0.0007183884,0.001394366,0.001262221,0.0009047993,0.002988277],"category_scores_gemma":[0.002558504,0.0006402474,0.0006857475,0.0006849354,0.0008512504,0.00115502,0.001066956,0.002247494,0.002217139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006732646,"about_ca_system_score_gemma":0.001082431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003062939,"about_ca_topic_score_gemma":0.005683023,"domain_scores_codex":[0.9985198,0.0001880258,0.00007511962,0.0005023521,0.0005402303,0.00017448],"domain_scores_gemma":[0.9976711,0.001033063,0.0002464563,0.0002896989,0.0006729692,0.00008680903],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005772638,0.00004719909,0.001490783,0.00009758682,0.00001699392,0.0000474693,0.00005424635,0.0003756619,0.9901251,0.000410028,0.0002535677,0.007023642],"study_design_scores_gemma":[0.000007538688,0.0001343725,0.003203084,0.00001370303,0.00002347268,0.0001367158,0.00003614611,0.004585739,0.9877893,0.0003032182,0.003739191,0.00002759179],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.4786823,0.003737404,0.4998092,0.001489826,0.0004712923,0.0007642334,0.003262898,0.002759671,0.009023211],"genre_scores_gemma":[0.6787435,0.004669591,0.3013729,0.001280799,0.0001644663,0.002031191,0.003595375,0.001055593,0.007086492],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.003062939,"threshold_uncertainty_score":0.009996772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01779548537046835,"score_gpt":0.2336610320868877,"score_spread":0.2158655467164193,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}