{"id":"W4312163929","doi":"10.1002/zaac.202200360","title":"Synthesis of Donor‐Stabilized Organogallium Complexes En Route to a Gallene","year":2022,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University","keywords":"Chemistry; Trifluoromethanesulfonate; Medicinal chemistry; Double bond; Carbene; Aldehyde; Gallium; Nucleophile; Nucleophilic substitution; Fluoride; Catalysis; Polymer chemistry; Stereochemistry; Organic chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009167303,0.0003521903,0.0002440992,0.0002101514,0.0001837416,0.0003416922,0.0004005719,0.0002799674,0.001567183],"category_scores_gemma":[0.0001091655,0.0001436468,0.0001455979,0.0001611298,0.0001127472,0.0001685102,0.0002328744,0.0002776151,0.0006103462],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005655538,"about_ca_system_score_gemma":0.0002426964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005193187,"about_ca_topic_score_gemma":0.001224787,"domain_scores_codex":[0.9999095,0.00001043597,0.000007068459,0.00002552709,0.00001975282,0.00002771066],"domain_scores_gemma":[0.9999449,0.000006640603,0.00001376717,0.000007545218,0.00001027077,0.00001695026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005354525,0.00001688473,0.00004061746,0.00006074755,0.000008867401,0.00004297532,0.00002165399,0.0002235619,0.9973984,0.0006121335,0.00007474999,0.001445916],"study_design_scores_gemma":[0.00002053504,0.0001360591,0.0001756743,0.00000457418,0.000009403761,0.00004956396,0.000007179566,0.00030833,0.9946141,0.000037566,0.004630888,0.000006252844],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9770248,0.00179827,0.009737448,0.00008722675,0.00007164129,0.0001277408,0.0005302756,0.00030149,0.01032117],"genre_scores_gemma":[0.9897156,0.0006365043,0.004853968,0.00003359565,0.000006176726,0.00005485425,0.0002996562,0.0000452559,0.004354462],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001567183,"threshold_uncertainty_score":0.005242765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01234332085650251,"score_gpt":0.2531944091615866,"score_spread":0.2408510883050841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}