{"id":"W4312589991","doi":"10.1039/d2gc04362a","title":"Spatial charge separation on the (110)/(102) facets of cocatalyst-free ZnIn<sub>2</sub>S<sub>4</sub>for the selective conversion of 5-hydroxymethylfurfural to 2,5-diformylfuran","year":2022,"lang":"en","type":"article","venue":"Green Chemistry","topic":"Catalysis for Biomass Conversion","field":"Engineering","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Canada First Research Excellence Fund","keywords":"Selectivity; Charge (physics); Photocatalysis; Chemistry; 5-hydroxymethylfurfural; Catalysis; Chemical engineering; Chemical physics; Materials science; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005005861,0.0003616812,0.000425403,0.0001041064,0.0003381548,0.00001990221,0.0008821537,0.000156044,0.00008691621],"category_scores_gemma":[0.0001200141,0.0002975918,0.0003437227,0.0006504498,0.0001258318,0.0001113532,0.0003762131,0.0003987062,0.00003104415],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003831722,"about_ca_system_score_gemma":0.00007541794,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001132914,"about_ca_topic_score_gemma":0.00003784484,"domain_scores_codex":[0.9978746,0.00004818049,0.0005183354,0.0004176923,0.0007237228,0.0004175015],"domain_scores_gemma":[0.9981654,0.0003034065,0.0002676236,0.0009850758,0.0001674239,0.0001110522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002443995,0.00006043668,0.0001781408,0.0002569705,0.0002451875,0.000001474631,0.0008481453,0.0028276,0.9888174,0.000006898004,0.004730572,0.001782786],"study_design_scores_gemma":[0.0009678103,0.0001344348,0.0005143089,0.0000293903,0.0001611929,0.000009800807,0.0004492311,0.02381584,0.9730065,0.00002761764,0.0005734965,0.0003103093],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965473,0.00009752464,0.0006693543,0.0004731505,0.0002601628,0.0008224434,0.0007375632,0.0001106483,0.0002817904],"genre_scores_gemma":[0.9989667,0.0000163785,0.00001701959,0.00007706918,0.0001319629,0.0001826659,0.0005043522,0.00006134184,0.00004250701],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02098824,"threshold_uncertainty_score":0.9999476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008126890424589165,"score_gpt":0.2039869820584488,"score_spread":0.1958600916338596,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}