{"id":"W4312665634","doi":"10.1039/d2qo01433e","title":"Fundamental curiosity of multivicinal inter-halide stereocenters","year":2022,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada","keywords":"Halide; Chemistry; Stereocenter; Halogen; Curiosity; Stereoselectivity; Alkane; Organic chemistry; Catalysis; Alkyl; Psychology; Enantioselective synthesis; Social psychology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004189003,0.0003114936,0.0003996892,0.00003272186,0.0005306366,0.00002421953,0.0007684347,0.000180387,0.03529824],"category_scores_gemma":[0.0001001423,0.0003819902,0.0001865821,0.0002840064,0.0003031045,0.0000753889,0.0007407996,0.001275492,0.00002531645],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007660128,"about_ca_system_score_gemma":0.0001785599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000234298,"about_ca_topic_score_gemma":0.000001646081,"domain_scores_codex":[0.9980081,0.0001378957,0.0005149472,0.0004970542,0.0003287425,0.0005132786],"domain_scores_gemma":[0.9988598,0.00009660136,0.0003104512,0.0004253973,0.00005517548,0.0002525489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003850198,0.0005782894,0.04310649,0.0001709761,0.0003018478,0.00005886084,0.0005167758,0.0000269986,0.8855128,0.000002348427,0.06729939,0.002040253],"study_design_scores_gemma":[0.002078273,0.00005980063,0.0002289287,0.000009164778,0.0001342496,0.0001776291,0.002692519,0.0003235493,0.8296463,0.00003323098,0.1642974,0.0003189139],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898759,0.0004595334,0.0002040837,0.000716428,0.001748024,0.0001987782,0.0002735688,0.0001205164,0.0064032],"genre_scores_gemma":[0.9876738,0.00002982463,0.0002877217,0.0004967002,0.0001945392,0.00002861929,0.0001258987,0.00005543206,0.01110753],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09699807,"threshold_uncertainty_score":0.9998632,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04315621059256762,"score_gpt":0.3538760942471012,"score_spread":0.3107198836545336,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}