{"id":"W4315606404","doi":"10.1021/acs.chemrev.2c00430","title":"Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere","year":2023,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":133,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Science and Technology Commission of Shanghai Municipality; Natural Sciences and Engineering Research Council of Canada; Shanghai Municipal Education Commission; National Natural Science Foundation of China","keywords":"Chemistry; Radical; Photodissociation; Atmosphere (unit); Reactive intermediate; Aerosol; Environmental chemistry; Atmospheric chemistry; Decomposition; Ozone; Photochemistry; Chemical physics; Organic chemistry; Catalysis; Meteorology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008532457,0.0005563205,0.001947737,0.000005843961,0.00005417018,0.00008091168,0.0009996369,0.0003549337,0.0004364692],"category_scores_gemma":[0.00419191,0.0003151381,0.0004053899,0.001154878,0.0001401467,0.0001361927,0.00003995663,0.0006989901,0.0003696276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003485195,"about_ca_system_score_gemma":0.0002741917,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000912582,"about_ca_topic_score_gemma":0.0007072177,"domain_scores_codex":[0.9972748,0.0001405109,0.00115677,0.0006931907,0.0002002538,0.0005345446],"domain_scores_gemma":[0.9963658,0.002604905,0.0004628775,0.000416627,0.00003630839,0.0001134317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00002366725,0.00009876471,0.0003001953,0.06901078,0.00003528911,0.00004368184,0.0005943878,0.000002183685,0.00005577039,0.000001300611,0.001747187,0.9280868],"study_design_scores_gemma":[0.0002471862,0.00003114388,0.000006697785,0.02077552,0.0001395718,0.00002303586,0.0001675843,0.00002235703,0.0001682937,0.00006499237,0.9778813,0.0004723],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.001351014,0.9957479,0.000006995005,0.00004059702,0.00009558375,0.002250963,0.0001126409,0.00003785271,0.0003565116],"genre_scores_gemma":[0.0001983371,0.9975068,0.0005456549,0.0001017403,0.0002855639,0.0003464086,0.0008018892,0.00002518073,0.0001884198],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9761341,"threshold_uncertainty_score":0.9999301,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08157315408041088,"score_gpt":0.3279828583859146,"score_spread":0.2464097043055037,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}