{"id":"W4315926060","doi":"10.1021/jacs.2c11858","title":"Remolding and Deconstruction of Industrial Thermosets via Carboxylic Acid-Catalyzed Bifunctional Silyl Ether Exchange","year":2023,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Graduate Education; Division of Chemistry; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Thermosetting polymer; Bifunctional; Silylation; Covalent bond; Ether; Organic chemistry; Catalysis; Polymer chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005030212,0.0001034952,0.0002946283,0.00002900276,0.0001000796,0.00002410813,0.0002352519,0.00006449142,0.00004846666],"category_scores_gemma":[0.0000802353,0.00006919591,0.0002441183,0.0004046092,0.0003662916,0.00008949278,0.0001347461,0.0002470838,0.000001962692],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007576853,"about_ca_system_score_gemma":0.00006148296,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008608084,"about_ca_topic_score_gemma":5.854703e-7,"domain_scores_codex":[0.9989237,0.00007218586,0.0003514445,0.0001277494,0.00032561,0.0001992967],"domain_scores_gemma":[0.9987453,0.0001483484,0.0008298749,0.000130418,0.00006331674,0.00008271117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006133279,0.00001407961,0.00177281,0.000008140056,0.0000416686,6.600114e-7,0.0003534725,0.00001668139,0.9893708,0.000004317381,0.0004708383,0.007885152],"study_design_scores_gemma":[0.0005202749,0.00004416884,0.001558356,0.00004898904,0.0000580954,0.0001138212,0.0003666288,0.0008205392,0.9959348,0.0002875699,0.0001469645,0.00009983507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982966,0.0002054878,0.0002087397,0.0007527316,0.0004369959,0.0000488283,0.000009353578,0.00001714528,0.00002412456],"genre_scores_gemma":[0.9978569,0.00006502009,0.001421378,0.0001587537,0.0004757579,0.000001173043,0.000001024526,0.00001193277,0.000008032716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007785317,"threshold_uncertainty_score":0.2821728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02242085951121903,"score_gpt":0.2519392089518839,"score_spread":0.2295183494406648,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}