{"id":"W4316662084","doi":"10.1002/anie.202216281","title":"Annulated Azuleno[2,1,8‐<i>ija</i>]azulenes: Synthesis and Properties","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Agencia Estatal de Investigación; Université de Montréal; York University","keywords":"Azulene; Annulene; Band gap; Molecule; Chemistry; Computational chemistry; Ring (chemistry); Materials science; Photochemistry; Organic chemistry; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001829563,0.0001990892,0.0001942374,0.0001175406,0.0001483373,0.0001369712,0.0002579186,0.0001218695,0.00173687],"category_scores_gemma":[0.0004244378,0.0001715594,0.00008313561,0.0001265762,0.000106098,0.0003281475,0.0001287408,0.0001156931,0.0001665241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007810698,"about_ca_system_score_gemma":0.00002905325,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007059221,"about_ca_topic_score_gemma":0.000005503103,"domain_scores_codex":[0.9987077,0.00001147515,0.0003008313,0.000329547,0.000407714,0.0002427792],"domain_scores_gemma":[0.9992524,0.0001924166,0.0001059825,0.0002188741,0.0001446375,0.00008563811],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001259873,0.00009332653,0.001340952,0.0002554828,0.0002384944,0.00002511979,0.0008575097,0.00001842046,0.939773,0.0001145976,0.04303143,0.01412573],"study_design_scores_gemma":[0.0002472685,0.000009837421,0.0007002476,0.0003414692,0.00003215107,0.00002810809,0.0005781907,0.0007762188,0.9657902,0.0007968525,0.03045972,0.0002397716],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9403667,0.00038918,0.00002811143,0.00364841,0.0006997866,0.00007912471,0.0001163484,0.0005530674,0.05411927],"genre_scores_gemma":[0.9948249,0.0005844317,0.00008883011,0.0001391145,0.000935082,0.000130413,0.0001993082,0.00003453744,0.003063326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05445826,"threshold_uncertainty_score":0.9991757,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02715314850637009,"score_gpt":0.233379949581329,"score_spread":0.2062268010749589,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}