{"id":"W4316810641","doi":"10.5194/amt-16-181-2023","title":"Development and validation of a new in situ technique to measure total gaseous chlorine in air","year":2023,"lang":"en","type":"article","venue":"Atmospheric measurement techniques","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; York University","funders":"Natural Environment Research Council; Natural Sciences and Engineering Research Council of Canada; Alfred P. Sloan Foundation; Horizon 2020 Framework Programme; H2020 European Research Council; Canada Research Chairs; Sight Research UK","keywords":"Chemistry; Chlorine; Mixing ratio; Alkyl; Spectrometer; Decomposition; In situ; Analytical Chemistry (journal); Dichloromethane; Environmental chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001183739,0.0002114278,0.0002982093,0.00001212593,0.00004271757,0.00001262474,0.0001746458,0.0001095475,0.0000957897],"category_scores_gemma":[0.0001216108,0.0002010039,0.00003160856,0.001135661,0.00002983967,0.0001618051,0.00003724671,0.0001453838,0.00001558657],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005467554,"about_ca_system_score_gemma":0.0001872272,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001164008,"about_ca_topic_score_gemma":0.001371125,"domain_scores_codex":[0.9981949,0.00004285119,0.000486044,0.0003674609,0.0005676954,0.0003410794],"domain_scores_gemma":[0.9994618,0.00002995396,0.0001001762,0.0002016898,0.00006310403,0.0001432297],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002539543,0.0001383515,0.2443916,0.0002593572,0.00003620202,0.0001055723,0.002207016,0.002457754,0.3414645,0.00002134902,0.0008825686,0.4077818],"study_design_scores_gemma":[0.0003072009,0.0001414065,0.1659893,0.0003699864,0.000006065627,0.00001434521,0.0002337042,0.0001107818,0.829678,0.0002307852,0.002581464,0.0003369516],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991749,0.0001631548,0.004596854,0.0001966497,0.00004099169,0.0008901241,0.000002338654,0.000261417,0.002099392],"genre_scores_gemma":[0.9239429,0.00003367949,0.07572336,0.00005171805,0.00003242882,0.00005484035,0.00001763372,0.00000800203,0.0001354054],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4882135,"threshold_uncertainty_score":0.81967,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03376024858591294,"score_gpt":0.2308667834652854,"score_spread":0.1971065348793725,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}