{"id":"W4317381179","doi":"10.1021/acsapm.2c01745","title":"Vilsmeier Complex Promotes Polycondensation of Imidodisulfuryl Chloride with Diols: Preparation of Ionic Oligomer Electrolytes","year":2023,"lang":"en","type":"article","venue":"ACS Applied Polymer Materials","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University; Hydro-Québec","funders":"Hydro-Québec","keywords":"Oligomer; Monomer; Electrolyte; Membrane; Condensation polymer; Ionic bonding; Ionic liquid; Polymer chemistry; Chloride; Chemistry; Ionic conductivity; Alkyl; Diol; Dimethylformamide; Ion; Polymer; Organic chemistry; Solvent; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002006237,0.0004308,0.0002124287,0.0001732873,0.0001174314,0.000236488,0.0002957605,0.0003119706,0.0008978443],"category_scores_gemma":[0.0002168925,0.0001412366,0.0001787774,0.0001461715,0.000173231,0.0003181133,0.0003192571,0.0003902404,0.0003788435],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002748834,"about_ca_system_score_gemma":0.00017191,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000229185,"about_ca_topic_score_gemma":0.0005567123,"domain_scores_codex":[0.9998648,0.00001968723,0.00001383953,0.0000383497,0.00003120497,0.00003202318],"domain_scores_gemma":[0.9998833,0.00002080058,0.00004035126,0.00001288283,0.00001853147,0.00002409819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002313616,0.00001415929,0.00005295203,0.00003761851,0.000004424706,0.00002894346,0.00003148772,0.00007139752,0.9980608,0.0001541415,0.00002651436,0.00149444],"study_design_scores_gemma":[0.000002076785,0.00003258679,0.00007678479,0.000001098379,0.000001984329,0.00002115272,0.000003133735,0.000172925,0.9990188,0.000005441662,0.0006623667,0.000001624857],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9840708,0.001399505,0.01160681,0.00008198454,0.00003033573,0.00003853926,0.00009038421,0.0001561464,0.002525584],"genre_scores_gemma":[0.9894219,0.0007174884,0.006421607,0.00003905921,0.00000904506,0.00002515022,0.0001114105,0.00004785918,0.003206444],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008978443,"threshold_uncertainty_score":0.003003597,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01204185300841738,"score_gpt":0.2347582248195599,"score_spread":0.2227163718111426,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}