{"id":"W4317725557","doi":"10.1039/d2tc04959g","title":"Trifluoroacetic acid prompted unexpected visible to NIR switching of ketoenamine-substituted triphenylamines","year":2023,"lang":"en","type":"article","venue":"Journal of Materials Chemistry C","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Army Research Office; Science and Engineering Research Board; Natural Sciences and Engineering Research Council of Canada","keywords":"Trifluoroacetic acid; Absorption (acoustics); Materials science; Photochemistry; Organic chemistry; Chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001002134,0.0002531337,0.00009568379,0.00008835253,0.000110732,0.0001575334,0.0002116871,0.0003011436,0.001142082],"category_scores_gemma":[0.0001304333,0.00009843722,0.0001381379,0.00008961992,0.0001551419,0.0002310037,0.0001209711,0.0004345667,0.000281544],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001059727,"about_ca_system_score_gemma":0.00008297068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002068372,"about_ca_topic_score_gemma":0.0004243044,"domain_scores_codex":[0.9999279,0.000009536378,0.00000325616,0.00001817995,0.00001071334,0.00003048458],"domain_scores_gemma":[0.9999191,0.00002335738,0.00002166338,0.000008522141,0.00001146849,0.000015923],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005039473,0.00000772462,0.00003383952,0.00002456713,0.000001726695,0.00007538404,0.00001798628,0.00002634542,0.9987794,0.0001131021,0.00003601325,0.0008334796],"study_design_scores_gemma":[0.000005752653,0.000109316,0.0005413609,0.000002764395,0.000003540867,0.0001138012,0.0000126275,0.0003090957,0.9981374,0.00003291638,0.0007284958,0.000002956057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910349,0.0005967016,0.004206909,0.00008449022,0.00003358024,0.0000155355,0.0001493553,0.00008648304,0.003792017],"genre_scores_gemma":[0.9973276,0.0002516868,0.001203706,0.00003792842,0.000004594475,0.000009774643,0.00006741411,0.00001416539,0.001083269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001142082,"threshold_uncertainty_score":0.003820658,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0144913061453251,"score_gpt":0.2594386732038636,"score_spread":0.2449473670585385,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}